191427-03-9

Basic information

• Product Name: Furan, 2,3-dihydro-2-phenyl-, (2S)-
• CAS NO: 191427-03-9
• Molecular Formula: C10H10O
• Molecular Weight: 146.189
• Mol File: 191427-03-9.mol
• Article Data: 33

Chemical Properties

• CAS DataBase Reference: Furan, 2,3-dihydro-2-phenyl-, (2S)-(CAS DataBase Reference)
• NIST Chemistry Reference: Furan, 2,3-dihydro-2-phenyl-, (2S)-(191427-03-9)
• EPA Substance Registry System: Furan, 2,3-dihydro-2-phenyl-, (2S)-(191427-03-9)

Safety Data

• Hazardous Substances Data: 191427-03-9(Hazardous Substances Data)

Upstream product

• 1191-99-7 2,3-dihydro-2H-furan 
• 591-50-4 iodobenzene 
• 17763-67-6 Phenyl triflate 
• 98-80-6 phenylboronic acid 
• 108-22-5 Isopropenyl acetate 
• 104516-09-8 1-phenylbuta-2,3-dien-1-ol 
• 108-95-2 phenol 

Downstream Products

• 1353720-78-1 C₁₉H₂₆O₄Si 
• 1353720-81-6 C₂₂H₃₂O₆ 

Relevant articles and documents

C1-Symmetric Binap Derivative Featuring Single Diferrocenylphosphino-Donor Moiety

A C1-symmetric chiral bisphosphine, FcPh-Binap (1), which possesses a single diferrocenylphosphino moiety together with a conventional Ph2P-substituent, was prepared in enantiomerically pure forms. Ligand 1 is sterically less demanding than Fc-Segphos (A)

Palladium complexes with chiral imidazole ligands as potential catalysts for asymmetric C[sbnd]C coupling reactions

Two palladium complexes of the type [Pd(im)2Cl2] containing chiral imidazole ligands (im?=?1-bornyloxymethylene imidazole, 1-fenchyloxymethylyne imidazole) were synthesized and structurally characterized. The square planar structure of one of the complexes was confirmed by the X-ray analysis. The new palladium complexes were tested as catalysts in various C[sbnd]C bond forming reactions, namely Suzuki–Miyaura, carbonylative Suzuki–Miyaura, asymmetric Heck-type coupling reactions and asymmetric conjugate addition of phenylboronic acid to heterocyclic acceptors. In all the reactions the cross-coupling products were obtained with high yield and selectivity under mild conditions. In case of coupling of 2,3-dihydrofuran with phenylboronic acid ee value ca. 10 was observed.

Synthesis, characterization and first application of chiral C2-symmetric bis(phosphinite)-Pd(II) complexes as catalysts in asymmetric intermolecular Heck reactions

A series of new chiral C2-symmetric bis(phosphinite) ligands and their palladium(II) complexes have been synthesized and for the first time used as catalysts in the palladium-catalysed asymmetric intermolecular Heck coupling reactions of 2,3-dihydrofuran with iodobenzene or aryl triflate. Under optimized conditions, products were obtained with high conversions and moderate to good enantioselectivities. The new C2-symmetric bis(phosphinite) ligands and their palladium(II) complexes were characterized using multinuclear NMR and Fourier transform infrared spectroscopies and elemental analysis.