191476-68-3

Basic information

• Product Name: 2,2-Dimethyl-cyclopropanecarbothioic acid S-(2,4,6-trimethyl-phenyl) ester
• CAS NO: 191476-68-3
• Molecular Weight: 248.389
• Mol File: 191476-68-3.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 2,2-Dimethyl-cyclopropanecarbothioic acid S-(2,4,6-trimethyl-phenyl) ester(CAS DataBase Reference)
• NIST Chemistry Reference: 2,2-Dimethyl-cyclopropanecarbothioic acid S-(2,4,6-trimethyl-phenyl) ester(191476-68-3)
• EPA Substance Registry System: 2,2-Dimethyl-cyclopropanecarbothioic acid S-(2,4,6-trimethyl-phenyl) ester(191476-68-3)

Safety Data

• Hazardous Substances Data: 191476-68-3(Hazardous Substances Data)

Upstream product

• 1541-10-2 mesitylthiol 
• 75885-59-5 2,2-dimethylcyclopropane-1-carboxylic acid 

Relevant articles and documents

Synthesis of alkylidenecyclopropanes via thermal cycloreversion of α-spirocyclopropyl-β-lactones

An efficient two-step synthesis of alkylidenecyclopropanes is reported based on the addition of metallated cyclopropyl thiol esters to carbonyl compounds. Thermolysis of the resulting α-spirocyclopropyl-β-lactones at 105-150°C induces thermal [2+2] cycloreversion to furnish alkylidenecyclopropanes in good yield.