19214-08-5

Basic information

• Product Name: AZEPAN-2-ONE OXIME
• Synonyms: HEXAHYDRO-2H-AZEPIN-2-ONE OXIME;AZEPAN-2-ONE OXIME;(2Z)-Azepan-2-one oxime;Hexahydro-1H-azepine-2-one oxime;2H-Azepin-7-aMine,3,4,5,6-tetrahydro-N-hydroxy-;N-(3,4,5,6-tetrahydro-2H-azepin-7-yl)hydroxylamine;N-[(2E)-azepan-2-ylidene]hydroxylamine
• CAS NO: 19214-08-5
• Molecular Formula: C₆H₁₂N₂O
• Molecular Weight: 128.17
• Product Categories: Ring Systems
• Mol File: 19214-08-5.mol
• Article Data: 1

Chemical Properties

• Melting Point: 168℃
• Boiling Point: 247.4°C at 760 mmHg
• Flash Point: 103.4°C
• Appearance: /
• Density: 1.19g/cm³
• Vapor Pressure: 0.00421mmHg at 25°C
• Refractive Index: 1.559
• CAS DataBase Reference: AZEPAN-2-ONE OXIME(CAS DataBase Reference)
• NIST Chemistry Reference: AZEPAN-2-ONE OXIME(19214-08-5)
• EPA Substance Registry System: AZEPAN-2-ONE OXIME(19214-08-5)

Safety Data

• Hazard Codes: Xn:Harmful
• Statements: R20/21/22:Harmful by inhalation, in contact with skin and if swallowed.; R36/37/38:Irritating to eyes, respiratory system
• Safety Statements: S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.; S36/37/39:Wear suitabl
• Hazardous Substances Data: 19214-08-5(Hazardous Substances Data)

Usage

General Description

Azepan-2-one oxime is a chemical compound with the molecular formula C6H11NO and a molecular weight of 113.16 g/mol. It is a heterocyclic oxime compound that is used in organic synthesis and pharmaceutical research. Azepan-2-one oxime is known for its ability to form complexes with metal ions and is also used as a ligand in coordination chemistry. It has potential applications in medicinal chemistry, particularly in the development of new drugs for various therapeutic purposes. Additionally, azepan-2-one oxime is used in the synthesis of other organic compounds and has been studied for its potential biological and pharmacological activities. Overall, this chemical compound has diverse and valuable applications in the field of chemistry and pharmaceutical research.

InChI:InChI=1/C6H12N2O/c9-8-6-4-2-1-3-5-7-6/h9H,1-5H2,(H,7,8)

Upstream product

• 7203-96-5 1-azacycloheptane-2-thione 
• 2525-16-8 O-methylcaprolactim 
• 39488-50-1 1-aza-2-methylthio-1-cycloheptene 

Downstream Products

• 85237-26-9 (E)-9-Phenyl-1,7,9-triaza-bicyclo[6.2.0]dec-7-en-10-one 
• 85237-27-0 (E)-9-(4-Chloro-phenyl)-1,7,9-triaza-bicyclo[6.2.0]dec-7-en-10-one 

Relevant articles and documents

Synthesis and Reactions of Cyclic Carbodiimides

Modified Tiemann rearrangement on cyclic amidoxime O-methanesulfonates 4 has been used to synthesize cycloalkylene carbodiimides 1 and 4,5,6,7-tetrahydrobenzo-1,3-diazonine (1g). 1,3-Diazacycloocta-1,2-diene (1b), n=5) was also prepared by dehydrosulfuration of pentamethylenethiourea. cycloadducts of the type 20 and 21 are readily formed from 1 as well as 1g with aryl isocyanates and N,N'-diphenylcarbodiimide.Hexafluoroacetone and 1d (n=7) give a dioxazane, 24b (n=7), while 1c (n=6) produces inseparable mixtures of 24a (n=6) and oxazetidine 23. 1,3-Diazacyclohepta-1,2-diene (1a, n=4) oligomerizes on preparation from tetramethylenethiourea, giving predominantly cyclodimer 7 and trimer 8 (not isolated); it can also be trapped with N,N'-diphenylcarbodiimide to give 20a (n=4, X=NC6H5).