195305-62-5

Basic information

• Product Name: (4-Bromo-phenyl)-bis-methylsulfanyl-thioacetic acid S-methyl ester
• Synonyms: (4-Bromo-phenyl)-bis-methylsulfanyl-thioacetic acid S-methyl ester
• CAS NO: 195305-62-5
• Molecular Weight: 337.326
• Mol File: 195305-62-5.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (4-Bromo-phenyl)-bis-methylsulfanyl-thioacetic acid S-methyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: (4-Bromo-phenyl)-bis-methylsulfanyl-thioacetic acid S-methyl ester(195305-62-5)
• EPA Substance Registry System: (4-Bromo-phenyl)-bis-methylsulfanyl-thioacetic acid S-methyl ester(195305-62-5)

Safety Data

• Hazardous Substances Data: 195305-62-5(Hazardous Substances Data)

Downstream Products

• 197314-05-9 2-(4-bromo-phenyl)-thiopropionic acid S-methyl ester 
• 53086-53-6 2-(4-bromophenyl)propionic acid 
• 197313-99-8 2-(4-bromo-phenyl)-2-methylsulfanyl-thiopropionic acid S-methyl ester 

Relevant articles and documents

Isomerization of Trimethyl α-Keto Trithioorthocarboxylates into α,α-Bis(methylthio) Thiolcarboxylates. A New Rearrangement of Synthetic Interest

A study was made of the isomerization reaction of a great variety of trimethyl α-keto trithioorthocarboxylates to α,α-bis(methylthio) thiolcarboxylates, intermediates of high synthetic value for the synthesis of α-arylpropionic acids. The reaction was carried out in methylene chloride in the presence of catalytic amounts of trityl perchlorate or methanesulfonic acid and was complete in 2 h at rt. In most of the investigated cases the result was positive, the yields usually being greater than 90%. Also the reaction mechanism was subjected to an experimental study.