19672-91-4

Basic information

• Product Name: N-benzyl-N-phenylbenzamide
• CAS NO: 19672-91-4
• Molecular Formula: C₂₀H₁₇NO
• Molecular Weight: 287.3551
• Mol File: 19672-91-4.mol
• Article Data: 17

Chemical Properties

• Boiling Point: 455°C at 760 mmHg
• Flash Point: 211.3°C
• Density: 1.16g/cm³
• Vapor Pressure: 1.83E-08mmHg at 25°C
• Refractive Index: 1.647
• CAS DataBase Reference: N-benzyl-N-phenylbenzamide(CAS DataBase Reference)
• NIST Chemistry Reference: N-benzyl-N-phenylbenzamide(19672-91-4)
• EPA Substance Registry System: N-benzyl-N-phenylbenzamide(19672-91-4)

Safety Data

• Hazardous Substances Data: 19672-91-4(Hazardous Substances Data)

Upstream product

• 91-73-6 N,N-dibenzylaniline 
• 758640-21-0 N-Benzylaniline 
• 98-88-4 benzoyl chloride 
• 538-51-2 benzylidene phenylamine 
• 93-98-1 N-phenyl benzoyl amide 
• 100-44-7 benzyl chloride 
• 61057-09-8 benzanilide ion 
• 18885-88-6 3-Methyl-4,5-diphenyl-4,5-dihydro-1,2,4-oxadiazole 
• 100-39-0 benzyl bromide 
• 100-52-7 benzaldehyde 
• 62-53-3 aniline 
• 591-50-4 iodobenzene 
• 1485-70-7 N-benzylbenzamide 
• 614-30-2 N-methyl-N-phenyl-benzenemethanamine 

Downstream Products

• 195141-41-4 N-benzyl-thiobenzanilide 
• 93-98-1 N-phenyl benzoyl amide 
• 100-44-7 benzyl chloride 
• 1007693-86-8 N-benzyl-2-hydroxy-N-phenylbenzamide 
• 172998-55-9 N-benzyl-2-methoxy-N-phenylbenzamide 
• 91-73-6 N,N-dibenzylaniline 
• 582-78-5 N-(4-methylphenyl)benzamide 
• 54343-55-4 3-Benzoyl-1-methyl-2-pyrrolidinone 

Relevant articles and documents

Regioselective Synthesis of 2° Amides Using Visible-Light-Induced Photoredox-Catalyzed Nonaqueous Oxidative C-N Cleavage of N, N-Dibenzylanilines

A visible-light-driven photoredox-catalyzed nonaqueous oxidative C-N cleavage of N,N-dibenzylanilines to 2° amides is reported. Further, we have applied this protocol on 2-(dibenzylamino)benzamide to afford quinazolinones with (NH4)2S2O8 as an additive. Mechanistic studies imply that the reaction might undergo in situ generation of α-amino radical to imine by C-N bond cleavage followed by the addition of superoxide ion to form amides.

Preparation of alkylated compounds using the trialkylphosphate

[Problem] trialkylphosphate strong base used reaction agent, a carboxylic acid, a ketone, an aldehyde, amine, amide, thiol, ester or Grignard reagent to a variety of substrates, and/or high efficiency to generate a highly stereoselective alkylation reaction, the alkylated compounds capable of producing new means. [Solution] was used as the alkylating agent in the alkylation of compound trialkylphosphate, strongly basic reaction production use. [Drawing] no

Facile amidation of esters with aromatic amines promoted by lanthanide tris (amide) complexes

The development of catalysts capable of catalyzing amidation of esters with amines to construct amides under mild conditions is of great importance. Compared to aliphatic amines, the direct catalytic amidation of esters with less nucleophilic aromatic amines is rather difficult. Employing simple lanthanide tris (amide) complexes Ln[N (SiMe3)2]3(μ-Cl)Li (THF)3 as the catalysts, it was found a broad range of aromatic amines and esters were efficiently converted into various amides in good yields under mild conditions. A plausible mechanism for this transformation was experimentally supported as starting from an amide exchange reaction between the lanthanide tris (amide) complex and the substrate amine.