197230-95-8

Basic information

• Product Name: N,N-dimethyl-2-[2-(phenyl)ethenyloxy]ethanamine
• Synonyms: N,N-dimethyl-2-[2-(phenyl)ethenyloxy]ethanamine
• CAS NO: 197230-95-8
• Molecular Weight: 191.273
• Mol File: 197230-95-8.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: N,N-dimethyl-2-[2-(phenyl)ethenyloxy]ethanamine(CAS DataBase Reference)
• NIST Chemistry Reference: N,N-dimethyl-2-[2-(phenyl)ethenyloxy]ethanamine(197230-95-8)
• EPA Substance Registry System: N,N-dimethyl-2-[2-(phenyl)ethenyloxy]ethanamine(197230-95-8)

Safety Data

• Hazardous Substances Data: 197230-95-8(Hazardous Substances Data)

Upstream product

• 591-50-4 iodobenzene 
• 3622-76-2 (2-ethenyloxyethyl)dimethylamine 

Downstream Products

• 101-49-5 2-(benzyl)-1,3-dioxolane 
• 364796-66-7 N,N-dimethyl-2-[2-(4-acetylphenyl)-2-phenylethenyloxy]ethanamine 
• 1282534-46-6 2-(1,2-di(4-trifluoromethylphenyl)-2-phenylethoxy)-N,N-dimethylethanamine 
• 1282534-43-3 2-(1,2,2-triphenylethoxy)-N,N-dimethylethanamine 
• 1282534-44-4 2-(1,2-di(4-acetylphenyl)-2-phenylethoxy)-N,N-dimethylethanamine 
• 53780-25-9 2-(2-methylphenyl)-2-phenylacetaldehyde 
• 50600-30-1 2-(4-methylphenyl)-2-(phenyl)acetaldehyde 

Relevant articles and documents

Highly regioselective, sequential, and multiple palladium-catalyzed arylations of vinyl ethers carrying a coordinating auxiliary: An example of a heck triarylation process

This article describes the development of new auxiliary-accelerated Heck multiarylations by intramolecular presentation of the oxidative addition complex. The introduction of a specific, palladium-coordinating dimethylamino group allows for the desired chelation-accelerated and chelation-controlled tri- and diarylation reactions. We report (a) the first example of a Heck triarylation process, (b) highly selective palladium-catalyzed diarylations of alkyl vinyl ethers, and (c) a very rapid two-phase protocol for the microwave-assisted hydrolysis of amino-substituted, arylated vinyl ethers constituting an entry to diarylated ethanals and substituted desoxybenzoins. X-ray structures and product patterns support the suggested substrate-controlled Heck reaction pathway. The catalyst-directing alkyl dimethylamino functionality was rapidly (1-2 min) and efficiently released by microwave hydrolysis after Heck multiarylation reactions. The liberated aromatic carbonyl compounds were thereafter isolated and fully characterized.