198142-61-9

Basic information

• Product Name: [Pd(3,5-dichloro-2,4,6-trifluorophenyl)2(1,5-cyclooctadiene)]
• CAS NO: 198142-61-9
• Molecular Weight: 614.538
• Mol File: 198142-61-9.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: [Pd(3,5-dichloro-2,4,6-trifluorophenyl)2(1,5-cyclooctadiene)](CAS DataBase Reference)
• NIST Chemistry Reference: [Pd(3,5-dichloro-2,4,6-trifluorophenyl)2(1,5-cyclooctadiene)](198142-61-9)
• EPA Substance Registry System: [Pd(3,5-dichloro-2,4,6-trifluorophenyl)2(1,5-cyclooctadiene)](198142-61-9)

Safety Data

• Hazardous Substances Data: 198142-61-9(Hazardous Substances Data)

Upstream product

• 105286-78-0 [Pd(η⁴-1,5-cyclooctadiene)(C₆F₅)₂] 

Downstream Products

• 514213-15-1 cis-[Pd(dimethylpyrazole)2(3,5-C₆Cl₂F₃)2] 
• 207393-49-5 cis-Pd(3,5-dichlorotrifluorophenyl)2(methyl isocyanide)2 
• 202280-78-2 cis-Pd(3,5-dichlorotrifluorophenyl)2(PPh₃)2 
• 207463-96-5 cis-Pd(3,5-dichlorotrifluorophenyl)2(PMe₃)2 
• 1427521-73-0 C₅₆H₆₆Cl₄F₆N₁₀O₄Pd 
• 1427521-75-2 C₄₂H₃₈Cl₄F₆N₁₀O₄Pd 
• 1427521-74-1 C₅₆H₆₆Cl₄F₆N₁₀O₄Pd 
• 1196660-12-4 cis-[Pd(3,5-dichloro-2,4,6-trifluorophenyl)2(bis(1,2-diphenylphospino)ethane)] 
• 1196660-15-7 cis-[Pd(3,5-dichloro-2,4,6-trifluorophenyl)2(SbPh₃)2] 
• 202280-80-6 cis-[Pd(3,5-dichloro-2,4,6-trifluorophenyl)2(AsPh₃)2] 
• 1196660-11-3 cis-[Pd(3,5-dichloro-2,4,6-trifluorophenyl)2(PMePh₂)2] 
• 1196660-14-6 cis-[Pd(3,5-dichloro-2,4,6-trifluorophenyl)2(AsPh₂Me)2] 
• 1196660-13-5 cis-[Pd(3,5-dichloro-2,4,6-trifluorophenyl)2(1,1'-bis(diphenylphospino)ferrocene)] 

Relevant articles and documents

Structural and dynamic studies in solution of anionic dinuclear azolato-bridged palladium(II) complexes

Detailed analysis of the 19F-NMR spectra of the boat-shaped complexes dimethylpyrazolate (dmpz), 2), HH- (head-to-head) and HT- (head-to-tail) (NBu4)2[Pd2(μ-LL)2 R4] (LL = 3-methylpyrazolate (mpz), 3; indazolate (indz), 4), (NBu4)2[Pd2(μ-dmpz)(μ-LL) R4] (LL = mpz, 6; indz, 7), and (NBu4)2 [R2Pd(μ-LL)2Pd (C6F5)2] (LL = pz, 8; dmpz, 9) affords valuable structural information in solution. The substituents of the azolate ligands, which reduce the dihedral angle between the coordination planes of the two metals, place the endo Fortho of different PdR2 fragments at short distances. A single-crystal X-ray structure has been obtained for compound HT-4 and the distances between Fortho compared with that calculated from the NMR spectra. The study of the dynamic processes for these complexes reveals the involvement of different mechanisms such as: (a) rotation of the R groups, (b) boat-boat inversion of the six-membered Pd(μ-LL)2Pd ring, (c)σ-1,2-metallotropic shift, and (d) associative exchange of PdR2 fragments between 1 and mononuclear complexes.