19881-82-4Relevant articles and documents
Tandem catalytic allylic amination and [2,3]-stevens rearrangement of tertiary amines
Soheili, Arash,Tambar, Uttam K.
supporting information; experimental part, p. 12956 - 12959 (2011/10/08)
We have developed a catalytic allylic amination involving tertiary aminoesters and allylcarbonates, which is the first example of the use of tertiary amines as intermolecular nucleophiles in metal-catalyzed allylic substitution chemistry. This process is
One-step synthesis of tertiary α-amino ketones and α-amino esters from amines and diazocarbonyl compounds
West,Glaeske,Naidu
, p. 977 - 980 (2007/10/02)
Diazoketones and diazoesters react with tertiary amines in the presence of copper powder to form transient ammonium ylides. These ylides undergo facile [1,2]-shift from N to C (Stevens rearrangement) of the best migrating group. Overall, α-substituted α-a
COPE-degradation in solution. 1
Graf,Graser,Sitzius
, p. 561 - 571 (2007/10/05)
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