19881-97-1

Basic information

• Product Name: (R)-3-phenylpropane-1,2-diol
• CAS NO: 19881-97-1
• Molecular Weight: 152.193
• Mol File: 19881-97-1.mol
• Article Data: 120

Chemical Properties

• CAS DataBase Reference: (R)-3-phenylpropane-1,2-diol(CAS DataBase Reference)
• NIST Chemistry Reference: (R)-3-phenylpropane-1,2-diol(19881-97-1)
• EPA Substance Registry System: (R)-3-phenylpropane-1,2-diol(19881-97-1)

Safety Data

• Hazardous Substances Data: 19881-97-1(Hazardous Substances Data)

Upstream product

• 86551-93-1 acetic acid 2-acetoxy-3-phenyl-propyl ester 
• 86151-59-9 1-Iodo-3-phenyl-2-propanol 
• 96-24-2 3-monochloro-1,2-propanediol 
• 4436-24-2 1,2-epoxy-3-phenylpropane 
• 5396-65-6 1-chloro-3-phenylpropan-2-ol 
• 104-53-0 3-phenyl-propionaldehyde 
• 300-57-2 allylbenzene 
• 828-01-3 phenyllactic acid 
• 71-36-3 butan-1-ol 
• 123394-79-6 (S)-2-(benzyloxy)-1-hydroxy-3-phenylpropane 
• 123394-77-4 (R)-2-(benzyloxy)-1-hydroxy-3-phenylpropane 
• 36960-03-9 2-oxo-3-phenylpropyl acetate 
• 173917-50-5 3-(benzyloxy)-1-phenylpropan-2-ol 
• 636580-94-4 (S,E)-N⁽³⁾-(3'-phenyl-prop-1'-enyl)-4-phenyl-5,5-dimethyloxazolidin-2-one 

Downstream Products

• 104762-40-5 4-Benzyl-2,2,2-triphenyl-2λ⁵-[1,3,2]dioxaphospholane 
• 68685-69-8 1-[4-benzyl-2-(2,4-dichloro-phenyl)-[1,3]dioxolan-2-ylmethyl]-1H-imidazole 
• 4436-24-2 1,2-epoxy-3-phenylpropane 
• 132871-52-4 1-azido-2-hydroxy-3-phenylpropane 
• 17131-14-5 (S)-(-)-3-phenyl-1,2-propanediol 
• 155498-78-5 Toluene-4-sulfonic acid (R)-2-hydroxy-3-phenyl-propyl ester 
• 86551-93-1 (2S)-3-phenyl-propane-1,2-diol diacetate 
• 112009-62-8 (R)-1-azido-3-phenylpropan-2-ol 
• 1300732-42-6 C₁₁H₁₅NO₂S 
• 1312719-37-1 Br^(1-)*C₁₅H₁₉N₂O₂⁽¹⁺⁾ 
• 1312719-43-9 Br^(1-)*C₁₃H₁₇N₂O⁽¹⁺⁾ 
• 1312887-98-1 C₂H₃O₂^(1-)*C₁₅H₁₉N₂O₂⁽¹⁺⁾ 
• 1312887-99-2 C₂F₃O₂^(1-)*C₁₅H₁₉N₂O₂⁽¹⁺⁾ 
• 1312719-31-5 C₁₁H₁₃BrO₂ 

Relevant articles and documents

Catalytic oxygen atom transfer promoted by tethered Mo(VI) dioxido complexes onto silica-coated magnetic nanoparticles

The preparation of three novel active and stable magnetic nanocatalysts for the selective liquid-phase oxidation of several olefins, has been reported. The heterogeneous systems are based on the coordination of cis-MoO2 moiety onto three different SCMNP@Si-(L1-L3) magnetically active supports, functionalized with silylated acylpyrazolonate ligands L1, L2 and L3. Nanocatalysts thoroughly characterized by ATR-IR spectroscopy, TGA and ICP-MS analyses, showed excellent catalytic performances in the oxidation of conjugated or unconjugated olefins either in organic or in aqueous solvents. The good magnetic properties of these catalytic systems allow their easy recyclability, from the reaction mixture, and reuse over five runs without significant decrease in the activity, either in organic or water solvent, demonstrating their versatility and robustness.

Lewis Base Catalyzed Dioxygenation of Olefins with Hypervalent Iodine Reagents

1,2-Diols are extremely useful building blocks in organic synthesis. Hypervalent iodine reagents are useful for the vicinal dihydroxylation of olefins to give 1,2-diols under metal-free conditions, but strongly acidic promoters are often required. Herein, we report a catalytic vicinal dioxygenation of olefins with hypervalent iodine reagents using Lewis bases as catalysts. The conditions are mild and compatible with various functional groups.

Cobalt-Catalyzed One-Pot Asymmetric Difunctionalization of Alkynes to Access Chiral gem-(Borylsilyl)alkanes

Enantioselective cobalt-catalyzed one-pot hydrosilylation and hydroboration of terminal alkynes has been developed employing a cobalt catalyst generated from Co(acac)2 and (R,R)-Me-Ferrocelane. A variety of terminal alkynes undergo this asymmetric transformation, affording the corresponding gem-(borylsilyl)alkane products with high enantioselectivity (up to 98 % ee). This one-pot reaction combines (E)-selective hydrosilylation of alkynes and consecutive enantioselective hydroboration of (E)-vinylsilanes with one chiral cobalt catalyst. This protocol represents the most straightforward approach to access versatile chiral gem-(borylsilyl)alkanes from readily available alkynes with commercially available cobalt salt and chiral ligand.