2016-83-3

Basic information

• Product Name: Benzene, 1-(3-chloro-1-propenyl)-3-nitro-
• CAS NO: 2016-83-3
• Molecular Formula: C9H8ClNO2
• Molecular Weight: 197.621
• Mol File: 2016-83-3.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: Benzene, 1-(3-chloro-1-propenyl)-3-nitro-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzene, 1-(3-chloro-1-propenyl)-3-nitro-(2016-83-3)
• EPA Substance Registry System: Benzene, 1-(3-chloro-1-propenyl)-3-nitro-(2016-83-3)

Safety Data

• Hazardous Substances Data: 2016-83-3(Hazardous Substances Data)

Upstream product

• 1504-64-9 (E)-3-(3-nitrophenyl)prop-2-en-1-ol 
• 1504-76-3 3-nitrocinnamaldehyde 
• 1504-64-9 3-(3-nitrophenyl)prop-2-en-1-ol 

Downstream Products

• 1504-64-9 3-(3-nitrophenyl)prop-2-en-1-ol 
• 91004-30-7 α-vinyl-m-nitrobenzyl alcohol 
• 952682-83-6 C₂₀H₂₃N₃O₃ 
• 63990-46-5 3-[3-(3-nitro-phenyl)-allyl]-8-propionyl-3,8-diaza-bicyclo[3.2.1]octane 

Relevant articles and documents

Ruthenium-catalyzed synthesis of allylic alcohols: Boronic acid as a hydroxide source

Secondary allylic alcohols were synthesized from linear allylic halides or carbonates using a catalytic amount of a ruthenium complex in the presence of boronic acid. The effects of solvent, base, ruthenium precursor, and boronic acid were fully explored, and the scope of the reaction was extended to various sub-strates. We also describe a preliminary investigation towards an enantioselective process.