203645-53-8Relevant articles and documents
A stable isotope deuterium-labeled organophosphorus insecticide method for the synthesis of
-
Paragraph 0069; 0070; 0073; 0074, (2016/10/09)
The invention relates to a synthesis method of a stable isotope deuterium-labeled organophosphorus insecticide. The synthesis method comprises the steps of: making stable isotope deuterium-labeled or natural abundance methyl alcohol react with phosphorus trichloride to generate a stable isotope deuterium-labeled dimethyl phosphite or trimethyl phosphite, and then making the stable isotope deuterium-labeled dimethyl phosphite or trimethyl phosphite react with stable isotope deuterium-labeled or natural abundance trichloracetic aldehyde to obtain the stable isotope deuterium-labeled organophosphorus insecticide. Compared with the prior art, the stable isotope deuterium-labeled trichlorphon or dichlorvos provided by the invention has the advantages that the chemical purity reaches above 98.0 percent and the isotope abundance reaches above 98.0 percent atomD after being separated and purified, thus fully meeting the demand on residue detection in the field of food safety.