203855-78-1

Basic information

• Product Name: methyl 2-((diphenylmethylene)amino)hexanoate
• Synonyms: methyl 2-((diphenylmethylene)amino)hexanoate
• CAS NO: 203855-78-1
• Molecular Weight: 309.408
• Mol File: 203855-78-1.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: methyl 2-((diphenylmethylene)amino)hexanoate(CAS DataBase Reference)
• NIST Chemistry Reference: methyl 2-((diphenylmethylene)amino)hexanoate(203855-78-1)
• EPA Substance Registry System: methyl 2-((diphenylmethylene)amino)hexanoate(203855-78-1)

Safety Data

• Hazardous Substances Data: 203855-78-1(Hazardous Substances Data)

Upstream product

• 109-65-9 1-bromo-butane 
• 81167-39-7 methyl N-(diphenylmethylene)glycinate 
• 1013-88-3 Benzophenone imine 
• 84393-11-3 <<(α-methoxy)hex-1-enyl>oxy>trimethylsilane 
• 3844-54-0 norleucine methyl ester hydrochloride 

Downstream Products

• 3844-54-0 norleucine methyl ester hydrochloride 

Relevant articles and documents

Synthesis of Hypervalent Iodine(III) Reagents Containing a Transferable (Diarylmethylene)amino Group and Their Use in the Oxidative Amination of Silyl Ketene Acetals

The preparation of some hypervalent iodine reagents containing a transferable amino group derived from benzophenone imine derivatives is reported. The reagents can be readily prepared and stored as a bench-stable solid, and were successfully used in the transition-metal-free oxidative amination of silyl ketene acetals to afford the corresponding α-amino esters, the benzophenone imine moieties of which could be easily hydrolyzed, thereby leading to the formation of primary amines.

Polyethylene glycol (PEG) as polymeric support and phase-transfer catalyst in the soluble polymer liquid phase synthesis of α-amino esters

α-Substituted α-amino esters were synthesized in liquid-phase by polyethylene glycol (PEG) promoted alkylation of a polyethylene glycol-supported Schiff base activated glycine ester.