204334-80-5Relevant articles and documents
Metal-Free Aminoiodination of Alkynes Under Visible Light Irradiation for the Construction of a Nitrogen-Containing Eight-Membered Ring System
Kanyiva, Kyalo Stephen,Marina, Tane,Nishibe, Shun,Shibata, Takanori
supporting information, p. 2746 - 2751 (2021/04/05)
A method for the synthesis of dihydrodibenzo[c,e]azocine derivatives via a regioselective intramolecular aminoiodination of alkynes under visible light irradiation has been developed. This protocol uses a combination of iodine and hypervalent iodine to re
Selective Synthesis of Phenanthrenes and Dihydrophenanthrenes via Gold-Catalyzed Cycloisomerization of Biphenyl Embedded Trienynes
Milián, Ana,Garciá-Garciá, Patricia,Pérez-Redondo, Adrián,Sanz, Roberto,Vaquero, Juan J.,Fernández-Rodríguez, Manuel A.
supporting information, p. 8464 - 8469 (2020/11/02)
Readily available o′-alkenyl-o-alkynylbiaryls, a particular type of 1,7-enynes, undergo a selective cycloisomerization reaction in the presence of a gold(I) catalyst to give interesting phenanthrene and dihydrophenanthrene derivatives in high yields. The solvent used provokes a switch in the evolution of the gold intermediate and plays a key role in the reaction outcome.
Synthesis of Naphthalenyl Triflates via the Cationic Annulation of Benzodiynes with Triflic Acid
Ge, Chenxin,Wang, Guohua,Wu, Panpan,Chen, Chao
supporting information, p. 5010 - 5014 (2019/07/08)
A highly efficient and regioselective annulation of benzodiynes promoted by triflic acid has been developed. This protocol provides a step and atom-economic access to a series of naphthalenyl triflates. Furthermore, direct synthetic applications of this r
