204716-14-3

Basic information

• Product Name: [Fe(C₆H₅CHCO)(CO)3]
• Synonyms: [Fe(C₆H₅CHCO)(CO)3]
• CAS NO: 204716-14-3
• Molecular Weight: 258.013
• Mol File: 204716-14-3.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: [Fe(C₆H₅CHCO)(CO)3](CAS DataBase Reference)
• NIST Chemistry Reference: [Fe(C₆H₅CHCO)(CO)3](204716-14-3)
• EPA Substance Registry System: [Fe(C₆H₅CHCO)(CO)3](204716-14-3)

Safety Data

• Hazardous Substances Data: 204716-14-3(Hazardous Substances Data)

Upstream product

• 201230-82-2 carbon monoxide 

Relevant articles and documents

Unusual reactions of cationic carbyne complexes of manganese and rhenium with [NMe4][HFe(CO)4] to form heteronuclear dimetal carbene-bridged complexes

The reaction of a cationic carbyne complex of manganese [Mn(≡CPh)(η-C5H5)(CO)2]BBr 4 1 with the salt [NMe4][HFe(CO)4] 3 in thf at low temperature gave [Mn(η-C5H5)(CO)3] 4 and a novel dimetal carbene-bridged complex [MnFe{μ-C(H)Ph}(η-C5H5)(CO)5] 5. The cationic rhenium carbyne complex [Re(≡CPh)(η-C5H5)-(CO)2]BBr 4 2 similarly reacted with 3 to give [Re(η-C5H5)(CO)3] 6 and [ReFe{μ-C(H)Ph}(η-C5H5)(CO)6] 7. Complex 5 reacted with carbon monoxide gas leading to cleavage of the μ-C-Mn and Mn-Fe bonds to afford 4 and a novel benzene-co-ordinated acyltricarbonyliron complex [Fe(PhCHCO)(CO)3] 8. The reaction of 7 with PPh3 yielded [ReFe{μ-C(H)Ph}(η-C5H5)(CO)5(PPh 3)] 9. The structures of complexes 5, 8 and 9 have been established by X-ray diffraction studies.