20579-79-7

Basic information

• Product Name: 3-amino-N-phenylphthalimide
• Synonyms: 3-amino-N-phenylphthalimide
• CAS NO: 20579-79-7
• Molecular Weight: 238.246
• Mol File: 20579-79-7.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: 3-amino-N-phenylphthalimide(CAS DataBase Reference)
• NIST Chemistry Reference: 3-amino-N-phenylphthalimide(20579-79-7)
• EPA Substance Registry System: 3-amino-N-phenylphthalimide(20579-79-7)

Safety Data

• Hazardous Substances Data: 20579-79-7(Hazardous Substances Data)

Upstream product

• 603-11-2 3-nitrophthalic acid 
• 62-53-3 aniline 
• 6296-53-3 3-acetylaminophthalic anhydride 
• 20871-13-0 3-acetylamino-N-phenylphthalimide 
• 5434-20-8 3-aminophthalic acid 

Downstream Products

• 35014-18-7 4-(2-hydroxy-naphthalen-1-ylazo)-2-phenyl-isoindole-1,3-dione 
• 110051-06-4 4-(4-hydroxy-phenylazo)-2-phenyl-isoindoline-1,3-dione 

Relevant articles and documents

Toward poly(aminophthalimide), structures of dimers and trimers

Poly(aminophthalimide) (PAP) dimers and trimers have been synthesized by palladium-catalyzed cross-coupling reactions of 3-aminophthalimides with 3-chloro- and 3,6-dichlorophthalimide, respectively. When Pd(OAc)2, XPhos (2-dicyclohexylphosphino-2′,4′,6′-triisopropylbiphenyl), and K3PO4 are used, the C-N bond-forming reactions proceed quantitatively. The structures of those oligomers are examined by experimental and theoretical techniques including NMR, IR, single-crystal X-ray diffraction, and DFT calculations. The strong preference for cisoid structure of the diphthalimidylamine unit bearing a bifurcate hydrogen bonding is disclosed. Therefore, the aminophthalimide backbone is a highly promising candidate for the construction of a dynamically ordered helical structure.