20614-06-6

Basic information

• Product Name: bis(4-bromobenzyl) ether
• Synonyms: bis(4-bromobenzyl) ether
• CAS NO: 20614-06-6
• Molecular Weight: 356.057
• Mol File: 20614-06-6.mol
• Article Data: 17

Chemical Properties

• CAS DataBase Reference: bis(4-bromobenzyl) ether(CAS DataBase Reference)
• NIST Chemistry Reference: bis(4-bromobenzyl) ether(20614-06-6)
• EPA Substance Registry System: bis(4-bromobenzyl) ether(20614-06-6)

Safety Data

• Hazardous Substances Data: 20614-06-6(Hazardous Substances Data)

Upstream product

• 873-75-6 4-bromobenzenemethanol 
• 589-15-1 1-bromomethyl-4-bromobenzene 
• 617-86-7 triethylsilane 
• 5798-75-4 Ethyl 4-bromobenzoate 
• 71-43-2 benzene 
• 1122-91-4 4-bromo-benzaldehyde 
• 108-88-3 toluene 
• 108-94-1 cyclohexanone 
• 583-60-8 2-Methylcyclohexanone 
• 584-08-7 potassium carbonate 
• 534-17-8 caesium carbonate 
• 766-77-8 Dimethylphenylsilane 

Downstream Products

• 106-38-7 para-bromotoluene 
• 1122-91-4 4-bromo-benzaldehyde 
• 938083-22-8 bis(4,4'-(3-chloro-4-methylphenylhydroxyboryl)benzyl) ether 
• 515157-44-5 DPB₁₆₃ 
• 1510826-88-6 (4-bromophenyl)(5-chloro-2-(1-(methoxyimino)ethyl)phenyl)methanone 
• 1373875-34-3 5-methyl-2-(pyridine-2-yl)phenyl 4-bromobenzoate 
• 83800-88-8 2-(4-bromophenyl)-3H-quinazolin-4-one 
• 57239-56-2 bis(4-bromobenzyl) selenide 
• 20883-11-8 (4-bomophenyl)(methyl)sulfide 
• 110929-20-9 (4’-bromobenzyl) 4-bromobenzoate 

Relevant articles and documents

Method for synthesizing ether by catalyzing alcohol through trimethyl halosilane

The invention discloses a method for synthesizing ether by catalyzing alcohol through trimethyl halosilane. According to the method, under the conditions of air or nitrogen atmosphere, no solvent andno transition metal catalyst, an alcohol compound is directly used as a raw material, trimethyl halosilane is used as a catalyst, and symmetric or asymmetric ether is synthesized through one-step selective dehydration reaction. According to the method, the use of strong acid, strong base and organic primary halides with high toxicity, instability and higher price is avoided, the synthesis steps are shortened, the synthesis efficiency is improved, the reaction has good selectivity, and a target ether product can be obtained preferentially.

Aryl Boronic Acid Catalysed Dehydrative Substitution of Benzylic Alcohols for C?O Bond Formation

A combination of pentafluorophenylboronic acid and oxalic acid catalyses the dehydrative substitution of benzylic alcohols with a second alcohol to form new C?O bonds. This method has been applied to the intermolecular substitution of benzylic alcohols to form symmetrical ethers, intramolecular cyclisations of diols to form aryl-substituted tetrahydrofuran and tetrahydropyran derivatives, and intermolecular crossed-etherification reactions between two different alcohols. Mechanistic control experiments have identified a potential catalytic intermediate formed between the aryl boronic acid and oxalic acid.

Efficient carbon-supported heterogeneous molybdenum-dioxo catalyst for chemoselective reductive carbonyl coupling

Reductive coupling of various carbonyl compounds to the corresponding symmetric ethers with dimethylphenylsilane is reported using a carbon-supported dioxo-molybdenum catalyst. The catalyst is air- and moisture-stable and can be easily separated from the reaction mixture for recycling. In addition, the catalyst is chemoselective, thus enabling the synthesis of functionalized ethers without requiring sacrificial ligands or protecting groups.