20754-20-5

Basic information

• Product Name: METHYL 4-METHYLCINNAMATE
• Synonyms: METHYL 4-METHYLCINNAMATE;(E)-3-p-Tolyl-acrylicacidmethylester;4-methyl-trans-cinnamicacidmethylester;E-3-p-Tolyl-acrylicacidmethylester;4-Methylcinnamic acid methyl ester;(E)-3-(4-Methylphenyl)acrylic acid methyl ester;(E)-4-Methylcinnamic acid methyl ester;4-Methylcinnamic acid methyl
• CAS NO: 20754-20-5
• Molecular Formula: C₁₁H₁₂O₂
• Molecular Weight: 176.21
• Product Categories: Aromatic Cinnamic Acids, Esters and Derivatives
• Mol File: 20754-20-5.mol
• Article Data: 329

Chemical Properties

• Melting Point: 60-61℃
• Boiling Point: 273℃
• Flash Point: 152℃
• Appearance: /
• Density: 1.057
• Vapor Pressure: 0.00591mmHg at 25°C
• Refractive Index: 1.553
• Storage Temp.: Sealed in dry,Room Temperature
• CAS DataBase Reference: METHYL 4-METHYLCINNAMATE(CAS DataBase Reference)
• NIST Chemistry Reference: METHYL 4-METHYLCINNAMATE(20754-20-5)
• EPA Substance Registry System: METHYL 4-METHYLCINNAMATE(20754-20-5)

Safety Data

• Hazard Codes: Xi
• Hazardous Substances Data: 20754-20-5(Hazardous Substances Data)

Usage

Synthesis Reference(s)

Synthetic Communications, 17, p. 1839, 1987 DOI: 10.1080/00397918708077329

InChI:InChI=1/C11H12O2/c1-9-3-5-10(6-4-9)7-8-11(12)13-2/h3-8H,1-2H3/b8-7+

Upstream product

• 67-56-1 methanol 
• 1866-39-3 4-methylcinnamic acid 
• 79-20-9 acetic acid methyl ester 
• 104-87-0 4-methyl-benzaldehyde 
• 96-32-2 bromoacetic acid methyl ester 
• 13565-07-6 4-methylcinnamoyl chloride 
• 459-44-9 4-methylbenzenediazonium tetrafluoroborate 
• 292638-85-8 acrylic acid methyl ester 
• 624-31-7 4-tolyl iodide 
• 1005421-77-1 tris(para-tolyl)antimony diacetate 
• 111873-48-4 (carbomethoxymethyl)dibutyltelluronium bromide 
• 74-88-4 methyl iodide 
• 21204-67-1 methyl (triphenylphosphoranylidene)acetate 
• 1070879-04-7 C₂₁H₁₉O₅PS 

Downstream Products

• 56955-36-3 methyl 3-(p-tolyl)propionate 
• 97116-17-1 meso-3,4-Bis-(4-methyl-phenyl)-adipinsaeure-dimethylester 
• 97116-17-1 meso-3,4-di-p-tolyl-adipic acid dimethyl ester 
• 122058-30-4 4-methylcinnamyl alcohol 
• 60456-15-7 (R,R)-methyl 2-bromo-3-methoxy-3-(p-methylphenyl)propanoate 
• 114671-13-5 methyl 3-(4'-methyl)phenyl-3-trimethylsilylpropanoate 
• 946-99-6 methyl 3-(4-bromomethyl)cinnamate 
• 139932-43-7 methyl 3-<(4'-methyl)phenyl>-3-methyldiphenylsilylpropanoate 
• 83341-74-6 2-Cyclohexyl-3,4,5,6-tetrahydro-t-6-(4-methylphenyl)-2H-1,2-oxazin-r-5-carbonsaeure-methylester 
• 131533-37-4 (2R,3S)-3-[(S)-(Dimethyl-phenyl-silanyl)-p-tolyl-methyl]-1-(4-methoxy-phenyl)-4-oxo-azetidine-2-carboxylic acid methyl ester 
• 138331-59-6 (2S,3S)-3-[(S)-(Dimethyl-phenyl-silanyl)-p-tolyl-methyl]-1-(4-methoxy-phenyl)-4-oxo-azetidine-2-carboxylic acid methyl ester 
• 50363-84-3 (Z)-methyl 3-(4-methylphenyl)propenoate 
• 1866-39-3 trans-p-methylcinnamic acid 
• 88738-86-7 methyl (E)-3-[4-(bromomethyl)phenyl]prop-2-enoate 

Relevant articles and documents

Polymetallic carbosilane dendrimers containing N, N'-iminopyridine chelating ligands: Applications in catalysis

This overview covers the most relevant results obtained by our group in the last few years concerning the synthesis and catalytic applications of metal complexes anchored to the surface of carbosilane dendrimers functionalized with iminopyridine ligands.

Synthesis, structure, and reactivity of palladacycles that contain a chiral rhenium fragment in the backbone: New cyclometalation and catalyst design strategies

The bromocyclopentadienyl complex f(η5-C5H 4Br)Re(CO)3] is converted to racemic [(η5- C5H4Br)Re-(NO)(PPh3)(CH2PPh 2)] (1b) similarly to a publish

Phosphine-Functionalized Chitosan Microparticles as Support Materials for Palladium Nanoparticles in Heck Reactions

Herein, we investigated the activation and stabilization of Pd nanoparticles using microparticles of chitosan-functionalized with phosphine moieties. The catalytic activity of the prepared material was assessed in a series of Heck reactions, which demonst

Triazine-hyperbranched polymer-modified magnetic nanoparticles-supported nano-cobalt for C–C cross-coupling reactions

Design of hyperbranched polymers (HBPs) and crafting them in catalytic systems especially in organic chemistry are a relatively unexplored domain. This paper reports the utilization of triazine-hyperbranched polymer (THBP)-coated magnetic chitosan nanoparticles (MCs) as stabilizing matrix for cobalt nanoparticles. Cobalt nanoparticles were fabricated by coordination cobalt(II) ions with amine-terminated triazine polymer and then reduced into Co(0) using sodium borohydride in aqueous medium. The Co(0)-THBP@MCs were fully characterized by FT-IR, SEM–EDX, TEM, and TGA analyses. The presence of metallic cobalt was determined by ICP and XRD techniques. This novel hyperbranched polyaromatic polymer-encapsulated cobalt nanoparticles showed high catalytic activity in Mizoroki–Heck and Suzuki–Miyaura cross-coupling reactions. Heck and Suzuki reactions were carried out using 0.35 and 0.4?mol% of cobalt nanoparticles in which the turnover number (TON) values were calculated as 271 and 225, respectively. In addition, the produced heterogeneous catalyst could be recovered and reused without considerable loss of activity. Oxygen stability and high reusability over 7 runs with trace leaching of the cobalt into the reaction media as well as moisture stability of the immobilized cobalt nanoparticles are their considerable worthwhile advantages.