2097-02-1Relevant articles and documents
METHOD FOR PRODUCING ARYLSILANE COMPOUND CONTAINING HALOSILANE COMPOUND AS RAW MATERIAL
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Paragraph 0059-0063, (2020/03/06)
PROBLEM TO BE SOLVED: To provide a method for producing an arylsilane compound with low production cost. SOLUTION: A method for producing an arylsilane compound includes a reaction step for the cross-coupling reaction of a halosilane compound represented by general formula (A-1), (A-2), or (A-3) and an arylboronic acid pinacol ester in the presence of a nickel catalyst, a Lewis acid catalyst, and an organic base (R independently represent an aromatic hydrocarbon group, a heteroaromatic ring group, or a C1-20 hydrocarbon group; X independently represent a halogeno group or a trifluoromethanesulfonyloxy group). SELECTED DRAWING: None COPYRIGHT: (C)2020,JPOandINPIT
B(C6F5)3-Catalyzed C-Si/Si-H Cross-Metathesis of Hydrosilanes
Ma, Yuanhong,Zhang, Liang,Luo, Yong,Nishiura, Masayoshi,Hou, Zhaomin
supporting information, p. 12434 - 12437 (2017/09/25)
The substituent redistribution of hydrosilanes on silicon through C-Si and Si-H bond cleavage and reformation is of great interest and importance, but this transformation is usually difficult to achieve in a selective fashion. By using electron-rich aromatic hydrosilanes, we have achieved for the first time the selective C-Si/Si-H bond homo- and cross-metathesis of a series of hydrosilanes in the presence of a boron catalyst B(C6F5)3. This protocol features simple reaction conditions, high chemoselectivity, wide substrate scope, and high functionality tolerance, offering a new pathway for the synthesis of multisubstituted functional silanes.
Synthesis, photophysical and electrochemical properties of symmetric silicon-linked coumarin-oxadiazole derivatives
Zhang, Lingling,Xia, Yan,Li, Min,Li, Dongfeng,Hou, Ruibin
, p. 7438 - 7442 (2016/11/11)
A novel, silicon-linked, symmetric, V-shaped, coumarin derivative (1) with an electron-deficient 1,3,4-oxadiazoles unit and a phenyl moiety was synthesized and characterized. An efficient multifunctional organic light-emitting diode material was obtained