210236-01-4

Basic information

• Product Name: Benzoic acid (Z)-3-methyl-pent-2-en-4-ynyl ester
• Synonyms: Benzoic acid (Z)-3-methyl-pent-2-en-4-ynyl ester
• CAS NO: 210236-01-4
• Molecular Weight: 200.237
• Mol File: 210236-01-4.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: Benzoic acid (Z)-3-methyl-pent-2-en-4-ynyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: Benzoic acid (Z)-3-methyl-pent-2-en-4-ynyl ester(210236-01-4)
• EPA Substance Registry System: Benzoic acid (Z)-3-methyl-pent-2-en-4-ynyl ester(210236-01-4)

Safety Data

• Hazardous Substances Data: 210236-01-4(Hazardous Substances Data)

Upstream product

• 50516-66-0 5-Trimethylsilyl-3-methyl-pent-1-en-4-in-3-ol 
• 3230-69-1 3-methyl-1-penten-4-yn-3-ol 
• 6153-05-5 (Z)-3-methylpent-2-en-4-ynol 
• 98-88-4 benzoyl chloride 

Downstream Products

• 79204-33-4 benzoic acid 3-methyl-furan-2-ylmethyl ester 

Relevant articles and documents

Efficient synthesis of functionalized furans via ruthenium-catalyzed cyclization of epoxyalkyne derivatives

Ruthenium catalyst TpRuPPh3(CH3CN)2Cl is found to effect the cyclization of epoxyalkynes to furans in the presence of Et3N. The reactions worked well for various epoxyalkynes with suitable oxygen and nitrogen functionalities with low loading of catalyst. It failed with disubstituted epoxyalkynes. The mechanism was elucidated by a deuterium labeling experiment that suggested that the mechanism involved a ruthenium-vinylidenium intermediate.