2113-47-5 Usage
Description
ACETAMIDOBIPHENYL is an organic compound with the molecular formula C14H11NO. It is a derivative of biphenyl, featuring an acetamido group attached to the biphenyl structure. ACETAMIDOBIPHENYL is known for its potential applications in various industries due to its unique chemical properties.
Uses
Used in Chemical Synthesis:
ACETAMIDOBIPHENYL is used as an intermediate in the synthesis of various compounds, including 2,2'',3,3'',4,4'',5,5'',6-Nonabromobiphenyl (N649580). This polybrominated biphenyl compound is known for its toxic effects on animals, humans, and the environment, and it is also a component of Firemaster FF-1, a polybrominated biphenyl fire retardant.
Used in Flame Retardants Industry:
In the flame retardants industry, ACETAMIDOBIPHENYL contributes to the production of Firemaster FF-1, a fire retardant that is used to reduce the flammability of materials. This application is crucial for enhancing the safety of various products, especially those used in electronic devices and construction materials.
Used in Environmental and Health Research:
Due to the toxic nature of 2,2'',3,3'',4,4'',5,5'',6-Nonabromobiphenyl, ACETAMIDOBIPHENYL plays a role in environmental and health research. Understanding the effects of this compound on ecosystems and human health is essential for developing safer alternatives and implementing regulations to minimize exposure and environmental contamination.
Check Digit Verification of cas no
The CAS Registry Mumber 2113-47-5 includes 7 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 4 digits, 2,1,1 and 3 respectively; the second part has 2 digits, 4 and 7 respectively.
Calculate Digit Verification of CAS Registry Number 2113-47:
(6*2)+(5*1)+(4*1)+(3*3)+(2*4)+(1*7)=45
45 % 10 = 5
So 2113-47-5 is a valid CAS Registry Number.
InChI:InChI=1/C14H13NO/c1-11(16)15-14-10-6-5-9-13(14)12-7-3-2-4-8-12/h2-10H,1H3,(H,15,16)
2113-47-5Relevant articles and documents
An N-Heterocyclic Carbene-Nickel Half-Sandwich Complex as a Precatalyst for Suzuki-Miyaura Coupling of Aryl/Heteroaryl Halides with Aryl/Heteroarylboronic Acids
Ando, Shin,Matsunaga, Hirofumi,Ishizuka, Tadao
, p. 1266 - 1272 (2018/06/18)
A nickel half-sandwich complex supported by our original NHC ligand was developed as a robust precatalyst for Suzuki-Miyaura cross-coupling. The addition of PPh3 was a crucial element in the suppression of side reactions and in accelerating the cross-coupling reaction. By employing the optimal conditions, aryl-aryl, heteroaryl-aryl, and heteroaryl-heteroaryl couplings were achieved.
REACTION OF DIAZONIUM SALTS WITH TRANSITION METALS X. FORMYLATION OF ARENEDIAZONIUM SALTS WITH CARBON MONOXIDE AND SILYL HYDRIDES UNDER PALLADIUM CATALYSIS
Kikukawa, Kiyoshi,Totoki, Takatoshi,Wada, Fumio,Matsuda, Tsutomu
, p. 283 - 288 (2007/10/02)
Arenediazonium tetrafluoroborates (ArN2BF4 where Ar = X-C6H4; X = H, 2-Me, 3-Me, 4-Me, 4-MeO, 4-MeCO, 4-EtOCO, 2-Ph, 2-Cl, 3-Cl, 4-Cl, 4-Br, 4-I, 3-NO2 and 4-NO2) were easily converted to aromatic aldehydes (ArCHO) in good yields through the palladium-catalyzed reaction with CO and Et3SiH or polymethylhydrosiloxane (PHMS) at room temperature.
