2121-66-6

Basic information

• Product Name: tetraethyl propane-1,1,3,3-tetracarboxylate
• Synonyms: 1,1,3,3-propanetetracarboxylic acid, tetraethyl ester; Tetraethyl 1,1,3,3-propanetetracarboxylate; Tetraethyl propane-1,1,3,3-tetracarboxylate
• CAS NO: 2121-66-6
• Molecular Formula: C₁₅H₂₄O₈
• Molecular Weight: 332.3463
• Mol File: 2121-66-6.mol
• Article Data: 1

Chemical Properties

• Boiling Point: 360.1°C at 760 mmHg
• Flash Point: 152.6°C
• Density: 1.142g/cm³
• Vapor Pressure: 2.27E-05mmHg at 25°C
• Refractive Index: 1.452
• CAS DataBase Reference: tetraethyl propane-1,1,3,3-tetracarboxylate(CAS DataBase Reference)
• NIST Chemistry Reference: tetraethyl propane-1,1,3,3-tetracarboxylate(2121-66-6)
• EPA Substance Registry System: tetraethyl propane-1,1,3,3-tetracarboxylate(2121-66-6)

Safety Data

• Hazardous Substances Data: 2121-66-6(Hazardous Substances Data)

Upstream product

• 126750-05-8 2,2-dimethyl-1,1,3,3-tetraethoxycarbonylpropane 
• 52204-95-2 N-(diphenylcarbamoyl)-aziridine 
• 105-53-3 diethyl malonate 
• 75-09-2 dichloromethane 

Downstream Products

• 2398-16-5 cis-1,3-cyclobutane dicarboxylic acid 
• 103100-77-2 2,4-bis-(2-hydroxy-3,5-dimethyl-benzyl)-glutaric acid diethyl ester 
• 2832-14-6 triethyl 1,1,3-propanetricarboxylate 
• 110-94-1 1,5-pentanedioic acid 
• 818-38-2 Diethyl glutarate 
• 10550-79-5 1,1,3,3-tetra(aminocarbonyl)propane 
• 102707-81-3 cyclohexane-1,1,3,3,5-pentacarboxylic acid pentaethyl ester 
• 10256-06-1 N,N',N'',N'''-tetraphenyl-propane-1,1,3,3-tetracarboxamide 
• 6221-56-3 1,5-Dihydroxy-2,4-di(hydroxymethyl)pentane 
• 67684-12-2 Aethyl-cyclohexan-1,1,2,2,4,4,5,5-octacarboxylat 
• 13102-40-4 1.1.3.3-Propantetracarbonsaeure-tetra-(N-benzyl)amid 
• 107398-58-3 1,5-diethoxycarbonyl-3,7-dimethyl-3,7-diazabicyclo<3,3,1>nona-2,6-dione 
• 107398-64-1 3,7-dibenzyl-1,5-diethoxycarbonyl-3,7-diazabicyclo<3,3,1>nona-2,6-dione 
• 109559-41-3 1,1,3,3-tetraethoxycarbonylcyclohexane 

Relevant articles and documents

Reaktionen mit Aziridinen (Aziranen), XXVI. Aminkatalysierte Amidoethylierungen von β-Dicarbonylverbindungen Eine einfache Synthese von 2-Methylpyrrol-1,3-dicarbonester

Esters of nonsubstituted and monosubstituted malonic, cyanoacetic, and β-keto acids are easily C-amidoethylated by N-acylaziridines in the presence of triethylamine.In this amine catalyzed reaction the acylaziridines show different degrees of reactivity.Often the products cannot be obtained by the known amidoethylation procedure or but in smaller yields.The new products 3g may smoothly be converted to the pyrroline 9 and further to the 2-methylpyrrole-1,3-dicarboxylate 10. - Divergent from earlier results, the primary amidoethylation product can be isolated from the known sodium salt reaction of tert-butyl acetoacetate with nonbulky acylaziridines.This product is cleaved by trifluoroacetic acid with remarkable easiness to yield the corresponding amidoethyl derivate of acetone.