21289-08-7

Basic information

• Product Name: 1,4-dilithio-1,2,3,4-tetraphenylbutadiene
• CAS NO: 21289-08-7
• Molecular Weight: 370.349
• Mol File: 21289-08-7.mol
• Article Data: 11

Chemical Properties

• CAS DataBase Reference: 1,4-dilithio-1,2,3,4-tetraphenylbutadiene(CAS DataBase Reference)
• NIST Chemistry Reference: 1,4-dilithio-1,2,3,4-tetraphenylbutadiene(21289-08-7)
• EPA Substance Registry System: 1,4-dilithio-1,2,3,4-tetraphenylbutadiene(21289-08-7)

Safety Data

• Hazardous Substances Data: 21289-08-7(Hazardous Substances Data)

Upstream product

• 7439-93-2 lithium 
• 501-65-5 diphenyl acetylene 

Downstream Products

• 102632-49-5 1,1-bis(1-methyl-2,3,4,5-tetraphenyl-1-silacyclopentadiene) 
• 88291-84-3 [Au₂(1,2,3,4-tetraphenylbuta-1,3-diene-1,4-diyl)(triphenylphosphine)2] 
• 16030-07-2 1-chloro-1,2,3,4,5-pentaphenyl-1-silacyclopentadiene 
• 1166986-92-0 1-phenyl-1-[4-(tert-butyldimethylsilyloxy)phenyl]-2,3,4,5-tetraphenylsilole 
• 55255-22-6 9,14-dihydro-9-phenyldibenz[a,c]anthracene 
• 752-28-3 hexaphenylsilole 
• 79343-32-1 1,1-dichloro-2,3,4,5-tetraphenyl-1H-silole 
• 55690-98-7 1,1-dibromo-2,3,4,5-tetraphenylstannole 
• 77904-13-3 1,1-diiodo-2,3,4,5-tetraphenylstannole 
• 97923-32-5 (CH₃)2Sn(C₄(C₆H₅)4Cl)Cl 
• 97923-33-6 (CH₃)2Sn(C₄(C₆H₅)4I)I 
• 21779-48-6 bis(1,2,3,4-tetraphenyl-1,3-butadien-1,4-ylidene)tin 
• 96969-76-5 Cl(CH₃)2SnC(C₆H₅)C₂(C₆H₅)2C(C₆H₅)I 
• 96969-75-4 (CH₃)2Sn(Br)C(C₆H₅)C(C₆H₅)C(C₆H₅)C(C₆H₅)Br 

Relevant articles and documents

Silole derivative, preparation method and application thereof, and lubricating grease

The invention provides a silole derivative, a preparation method and application thereof, and lubricating grease containing the silole derivative. The silole derivative disclosed by the invention hasa structure shown as a formula (I), wherein the definiti

Blue-shifted aggregation-induced emission of siloles by simple structural modification and their application as nitro explosive chemosensors

To induce blue-shifted emission of siloles, two tolyl-substituted derivatives-1,1-diphenyl-2,3,4,5-tetra(m-tolyl)-1H-silole (m-TS) and 1,1-diphenyl-2,3,4,5-tetra(o-tolyl)-1H-silole (o-TS)-were prepared, and their photophysical properties were compared with those of a reference compound, hexaphenylsilole (HPS). By substituting methyl groups at ortho positions of peripheral tetraphenyl rings on the silacyclopentadiene ring, intramolecular rotations could be successfully controlled and the photophysical properties were varied, while substituting methyl groups at meta positions showed similar photophysical properties compared with the case of HPS. That is, simple structural modification at the ortho position significantly affects the geometry and the photophysical properties of silole, which leads to blue-shifted emission. Finally, two tolyl-substituted siloles and HPS were employed as chemosensors for the detection of nitro explosives, and o-TS showed the highest sensing ability.

Supported thin flexible polymethylhydrosiloxane permeable films functionalised with silole groups: New approach for detection of nitroaromatics

Novel re-useable luminescent sensors highly sensitive to quenching by nitroaromatic compounds in both solution and the vapour phase have been developed by covalently bonding a new allyl-substituted silole into substrate-supported crosslinked polymethylhyd