213825-55-9

Basic information

• Product Name: D-(1,5-13C₂)arabinose
• CAS NO: 213825-55-9
• Molecular Weight: 152.109
• Mol File: 213825-55-9.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: D-(1,5-13C₂)arabinose(CAS DataBase Reference)
• NIST Chemistry Reference: D-(1,5-13C₂)arabinose(213825-55-9)
• EPA Substance Registry System: D-(1,5-13C₂)arabinose(213825-55-9)

Safety Data

• Hazardous Substances Data: 213825-55-9(Hazardous Substances Data)

Upstream product

• 90913-08-9 [4-13C]-D-erythrose 

Downstream Products

• 101615-89-8 D-(1,3,6-13C3)allose 
• 101615-89-8 D-(1,3,6-13C3)altrose 
• 139657-61-7 D-(2,5-13C₂)ribose 

Relevant articles and documents

Two-bond 13C-13C spin-coupling constants in carbohydrates: New measurements of coupling signs

D-(1,3,6-13C3)Allose (1), (13C)methyl α-D-(1,2-13C2)glucopyranoside (2) and (13C)methyl β-D-(1,2-13C2)glucopyranoside (3) were synthesized and used to establish the signs of their constituent 2J(CCC) or 2J(COC) values (2J(C1,C3) in the α-pyranose of 1 (15), and 2J(C1,CH3) in 2 and 3). Compounds 2, 3 and 15 contain three mutually coupled labeled carbons, thus creating a three-spin system from which crosspeak displacements in 13C-13C COSY-45 spectra were used to determine coupling signs. In all compounds, at least one 3J(CC) value was present as an internal reference: 3J(C2,CH3 in 2 and 3, and 3J(C1,C6) and 3J(C3,C6) in 15. 2J(C1,CH3), in 2 and 3, and 2J(C1,C3) in 15, were found to be negative, thus providing experimental confirmation of the sign predictions made via the projection resultant rule described recently.