21397-40-0

Basic information

• Product Name: N-(4-Methylphenyl)-N-phenylbenzamide
• Synonyms: N-(4-Methylphenyl)-N-phenylbenzamide
• CAS NO: 21397-40-0
• Molecular Weight: 287.361
• Mol File: 21397-40-0.mol
• Article Data: 4

Chemical Properties

• CAS DataBase Reference: N-(4-Methylphenyl)-N-phenylbenzamide(CAS DataBase Reference)
• NIST Chemistry Reference: N-(4-Methylphenyl)-N-phenylbenzamide(21397-40-0)
• EPA Substance Registry System: N-(4-Methylphenyl)-N-phenylbenzamide(21397-40-0)

Safety Data

• Hazardous Substances Data: 21397-40-0(Hazardous Substances Data)

Upstream product

• 591-50-4 iodobenzene 
• 582-78-5 N-(4-methylphenyl)benzamide 
• 4903-36-0 N-phenyl-benzimidoyl chloride 
• 93-98-1 N-phenyl benzoyl amide 
• 624-31-7 4-tolyl iodide 
• 1189-71-5 isocyanate de chlorosulfonyle 
• 29119-37-7 α,N-diphenyl-α-(4-methyl phenyl) nitrone 
• 620-84-8 4-methyldiphenylamine 
• 98-88-4 benzoyl chloride 
• 101-84-8 diphenylether 

Downstream Products

• 65-85-0 benzoic acid 
• 102007-17-0 2-nitro-benzoic acid-(phenyl-p-tolyl-amide) 
• 109866-39-9 anthranilic acid-(phenyl-p-tolyl-amide) 
• 620-84-8 4-methyldiphenylamine 

Relevant articles and documents

Efficient synthesis of tertiary acyclic amides by the Chapman rearrangement of aryl benzimidates in ionic liquids

The Chapman rearrangement of aryl N-arylbenzimidates to tertiary acyclic amides is accelerated in ionic liquids and proceeds at lower temperatures as 120-190°C.

A simple copper-catalyzed synthesis of tertiary acyclic amides

The N-arylation of aromatic and aliphatic secondary acyclic amides, known to be poor nucleophiles, has been accomplished using a simple and cheap copper catalytic system. The corresponding tertiary acyclic amides, which can be found in numerous biologically active compounds, have been obtained in good to excellent yields.