214215-29-9

Basic information

• Product Name: (R)-(2-(4-methoxyphenyl)-propylidene)-carbamic acid methyl ester
• Synonyms: (R)-(2-(4-methoxyphenyl)-propylidene)-carbamic acid methyl ester
• CAS NO: 214215-29-9
• Molecular Weight: 221.256
• Mol File: 214215-29-9.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (R)-(2-(4-methoxyphenyl)-propylidene)-carbamic acid methyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: (R)-(2-(4-methoxyphenyl)-propylidene)-carbamic acid methyl ester(214215-29-9)
• EPA Substance Registry System: (R)-(2-(4-methoxyphenyl)-propylidene)-carbamic acid methyl ester(214215-29-9)

Safety Data

• Hazardous Substances Data: 214215-29-9(Hazardous Substances Data)

Upstream product

• 922-68-9 Methyl glyoxylate 
• 6298-96-0 1(R)-(4-methoxyphenyl)-ethylamine 

Downstream Products

• 214215-57-3 3-chloro-1-[1-(4-methoxyphenyl)-ethyl]-4-oxo-3-phenyl-azetidine-2-carboxylic acid methyl ester 
• 214215-55-1 3,3-dichloro-1-[1-(4-methoxyphenyl)-ethyl]-4-oxo-azetidine-2-carboxylic acid methyl ester 

Relevant articles and documents

Stereoselective synthesis of racemic α-amino-acid derivatives with a β-lactam skeleton: Application of the Staudinger reaction to chiral imines of methyl glyoxylate

Selected imines of methyl glyoxylate act as good partners in the Staudinger cycloaddition reaction with a series of substituted ketenes. The cis stereoselectivity is almost complete with electron-donor substituted ketenes, but the asymmetric induction is low when imines derived from chiral l-aryl-ethylamines are used.