21559-73-9

Basic information

• Product Name: cyclohexyl 2-(acetylamino)-2-deoxy-α-D-glucopyranoside
• Synonyms: cyclohexyl 2-(acetylamino)-2-deoxy-α-D-glucopyranoside
• CAS NO: 21559-73-9
• Molecular Weight: 303.356
• Mol File: 21559-73-9.mol
• Article Data: 5

Chemical Properties

• CAS DataBase Reference: cyclohexyl 2-(acetylamino)-2-deoxy-α-D-glucopyranoside(CAS DataBase Reference)
• NIST Chemistry Reference: cyclohexyl 2-(acetylamino)-2-deoxy-α-D-glucopyranoside(21559-73-9)
• EPA Substance Registry System: cyclohexyl 2-(acetylamino)-2-deoxy-α-D-glucopyranoside(21559-73-9)

Safety Data

• Hazardous Substances Data: 21559-73-9(Hazardous Substances Data)

Upstream product

• 7512-17-6 N-Acetyl-D-glucosamine 
• 108-93-0 cyclohexanol 
• 21559-74-0 cyclohexyl 3,4,6-tri-O-acetyl-2-(acetylamino)-2-deoxy-α-D-glucopyranoside 
• 1040191-33-0 N'-(2-acetamido-2-deoxy-β-D-glucopyranosyl)-p-toluenesulfono-hydrazide 
• 3068-34-6 Acetic acid (2R,3S,4R,5R,6R)-3-acetoxy-2-acetoxymethyl-5-acetylamino-6-chloro-tetrahydro-pyran-4-yl ester 
• 187738-48-3 cyclohexyl 2-acetamido-3,6-tri-O-benzoyl-2-deoxy-α-D-glucopyranoside 
• 187738-49-4 cyclohexyl 2-acetamido-3,4,6-tri-O-benzoyl-2-deoxy-α-D-glucopyranoside 
• 187738-47-2 cyclohexyl 2-acetamido-4,6-di-O-benzoyl-2-deoxy-α-D-glucopyranoside 

Downstream Products

• 624738-78-9 (R)-4-{(S)-2-[(R)-2-((4aR,6S,7R,8R,8aS)-7-Acetylamino-6-cyclohexyloxy-2,2-dimethyl-hexahydro-pyrano[3,2-d][1,3]dioxin-8-yloxy)-propionylamino]-propionylamino}-4-carbamoyl-butyric acid benzyl ester 
• 624738-69-8 (R)-4-{(S)-2-[(R)-2-((2S,3R,4R,5S,6R)-3-Acetylamino-2-cyclohexyloxy-5-hydroxy-6-hydroxymethyl-tetrahydro-pyran-4-yloxy)-propionylamino]-propionylamino}-4-carbamoyl-butyric acid benzyl ester 
• 624738-74-5 cyclohexyl 2-(acetylamino)-2-deoxy-4,6-O-isopropylidene-3-O-[(R)-1-carboxyethyl]-α-D-glucopyranoside 
• 187738-42-7 N-((2S,3R,4R,5S,6R)-2-Cyclohexyloxy-4,5-dimethoxy-6-methoxymethyl-tetrahydro-pyran-3-yl)-N-methyl-acetamide 
• 499104-65-3 N-((3R,4R,5S,6R)-2-Cyclohexyloxy-4,5-dihydroxy-6-hydroxymethyl-tetrahydro-pyran-3-yl)-acetamide 
• 509086-48-0 cyclohexyl 2-(acetylamino)-2-deoxy-4,6-O-isopropylidene-α-D-glucopyranoside 

Relevant articles and documents

Protecting group free glycosidations using p-toluenesulfonohydrazide donors

(Figure Presented) N-Glycopyranosylsulfonohydrazides are introduced as glycosyl donors for protecting group free synthesis of O-glycosides, glycosyl azides, and oxazolines. Mono- and disaccharides containing a reducing terminal N-acelylglucosamine residue were condensed with p-toluenesulfonylhydrazide to give the desired β-D-pyranose donors. These donors can be activated with NBS and then glycosidated with the desired alcohol or transformed to the oxazoline or glycosyl azide.

The synthesis of α-glycosides of methyl N-acetylmuramyl-L-alanyl-D-isoglutaminate

1-Heptanol, cyclohexanol, and cholesterol were glycosylated with α-glucosaminylchloride peracetate in the presence of HgI2 at 80-90°C to the corresponding peracetylated α-glycosides of N-acetylglucosamine. Successive Zemplen deacetylation, benz

Anomeric C-19-steroid N-acetylglucosaminides.

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