222306-90-3

Basic information

• Product Name: S-(tert-butyl)-S-phenylsulfoximine
• Synonyms: S-(tert-butyl)-S-phenylsulfoximine
• CAS NO: 222306-90-3
• Molecular Weight: 197.301
• Mol File: 222306-90-3.mol
• Article Data: 4

Chemical Properties

• CAS DataBase Reference: S-(tert-butyl)-S-phenylsulfoximine(CAS DataBase Reference)
• NIST Chemistry Reference: S-(tert-butyl)-S-phenylsulfoximine(222306-90-3)
• EPA Substance Registry System: S-(tert-butyl)-S-phenylsulfoximine(222306-90-3)

Safety Data

• Hazardous Substances Data: 222306-90-3(Hazardous Substances Data)

Upstream product

• 89902-44-3 S-methyl-S-phenyl-N-(trimethylsilyl)sulfoximine 
• 4381-25-3 S-methyl-S-phenylsulfoximine 
• 1193-82-4 racemic methyl phenyl sulfoxide 
• 100-68-5 methyl-phenyl-thioether 
• 74-88-4 methyl iodide 
• 222306-91-4 S-tert-butyl-N-trimethylsilyl-S-phenylsulfoximine 

Downstream Products

• 222306-91-4 S-tert-butyl-N-trimethylsilyl-S-phenylsulfoximine 
• 864811-52-9 N-allyl-S-tert-butyl-S-phenylsulfoximine 
• 864811-51-8 S-tert-butyl-N-2-methoxyethyl-S-phenylsulfoximine 
• 200135-59-7 S-tert-butyl-N-methyl-S-phenylsulfoximine 

Relevant articles and documents

The tert-butyl sulfoximine group as an effective ortho-director of lithiation: Ortho-metallated S-(tert-butyl)-S-phenylsulfoximines

The readily available S-(tert-butyl)-N-(trimethylsilyl)-S- phenylsulfoximine was prepared from S-methyl-N(trimethylsilyl)-S- phenylsulfoximine via lithiation-methylation sequences. The reaction with n- butyllithium in THF at -78°C afforded the correspondi

An unexpected cyclization reaction of tert-butyl o-trimethylsilylphenyl sulfoximine

An efficient one-pot synthesis of the title compound 5 starting from methyl phenyl sulfoximine is described. On attempted iododesilylation of this compound using iodine chloride, one methyl group on the silicon atom is formally replaced by the imino nitrogen to give a derivative 8 of the novel heterocyclic system 1,3,2-benzothiasilazole. ARKAT-USA, Inc.