22567-15-3Relevant articles and documents
Stoichiometric Hydroboration-Oxidation Reaction of Monocyclic Monoterpenoids: A Mechanistic Approach
Khanna, Vijay,Ladwa, P. H.
, p. 816 - 822 (2007/10/02)
The stoichiometric studies on hydroboration-oxidation reactions of (-)-carvone have been carried out to gain an insight into the mechanism of formation of unusual products 2-oxo-p-menth-9-ols (IVb,c), p-menth-2,9-diols (Xa,b) and p-menth-1-en-9-ol (VII).Based on high resolution PMR spectral data, the stereochemistry of IVb,c and Xa,b has been deduced.Similiar studies have been extended to (+)-dihydrocarvone and (-)-carveol.