226212-46-0

Basic information

• Product Name: ((Z)-1-Bromo-9-methoxy-5,9-dimethyl-dec-2-ene-2-sulfinyl)-benzene
• Synonyms: ((Z)-1-Bromo-9-methoxy-5,9-dimethyl-dec-2-ene-2-sulfinyl)-benzene
• CAS NO: 226212-46-0
• Molecular Weight: 401.408
• Mol File: 226212-46-0.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: ((Z)-1-Bromo-9-methoxy-5,9-dimethyl-dec-2-ene-2-sulfinyl)-benzene(CAS DataBase Reference)
• NIST Chemistry Reference: ((Z)-1-Bromo-9-methoxy-5,9-dimethyl-dec-2-ene-2-sulfinyl)-benzene(226212-46-0)
• EPA Substance Registry System: ((Z)-1-Bromo-9-methoxy-5,9-dimethyl-dec-2-ene-2-sulfinyl)-benzene(226212-46-0)

Safety Data

• Hazardous Substances Data: 226212-46-0(Hazardous Substances Data)

Upstream product

• 20451-53-0 Phenyl vinyl sulfoxide 
• 3613-30-7 7-methoxy-3,7-dimethyloctanal 
• 474383-40-9 2-benzenesulfinyl-9-methoxy-5,9-dimethyl-dec-1-en-3-ol 

Relevant articles and documents

Radical β-elimination of a sulfinyl group to afford allenes

An unprecedented radical β-elimination of vinyl sulfoxides has opened a new route to functionalized allenes. The radical precursors were obtained in two steps from a carbonyl derivative and a vinyl sulfoxide. The radical translocation stratagem could also be used to trigger the β-elimination of the sulfinyl radical. Variation of the nature of the sulfur group on a common precursor gave no allene with the thio, sulfonyl, and iminosulfinyl moieties, in contrast to the analogous vinyl sulfoxide and vinylsulfimide precursors. Wiley-VCH Verlag GmbH, 69451 Weinheim, Germany, 2002.