230310-66-4Relevant articles and documents
Synthesis and use of water-soluble sulfonated dibenzofuran-based phosphine ligands
Sollewijn Gelpke, Arjan E.,Veerman, Johan J.N.,Goedheijt, Marcel Schreuder,Kamer, Paul C.J.,Van Leeuwen, Piet W.N.M.,Hiemstra, Henk
, p. 6657 - 6670 (2007/10/03)
The syntheses of three triphenylphosphine analogues with one, two or three phenyl groups replaced by 2-dibenzofuranyl groups, respectively, and one enantiopure analogue of the atropisomeric diphosphine MeO-BIPHEP with all four phenyl groups replaced by 2-dibenzofuranyl are reported. Sulfonation of these compounds with sulfuric acid at rt proceeded with complete regioselectivity at the 8-position in the dibenzofuran moieties. These results proved the usefulness of dibenzofuran as a structural moiety in the synthesis of water-soluble phosphine ligands. The dibenzofuran-based, water- soluble triphenylphosphine analogues were used as ligands in palladium- catalysed aqueous phase Heck and Suzuki reactions and in the rhodium- catalysed two-phase hydroformylation of propene.
