2350-89-2

Basic information

• Product Name: 4-VINYLBIPHENYL
• Synonyms: Biphenyl, 4-vinyl-;p-Vinylbiphenyl;NSC 58060;PARA-PHENYLSTYRENE;4-Ethenylbiphenyl;1-ethenyl-4-phenylbenzene;1-ethenyl-4-phenyl-benzene;1-phenyl-4-vinyl-benzene
• CAS NO: 2350-89-2
• Molecular Formula: C₁₄H₁₂
• Molecular Weight: 180.25
• EINECS: 219-082-6
• Product Categories: Styrenes;Fluorenes, etc. (reagent for high-performance polymer research);Functional Materials;Reagent for High-Performance Polymer Research;Biphenyl series
• Mol File: 2350-89-2.mol
• Article Data: 124

Chemical Properties

• Melting Point: 119-121 °C(lit.)
• Boiling Point: 301.7 °C at 760 mmHg
• Flash Point: 139.4 °C
• Appearance: /
• Density: 0.997
• Vapor Pressure: 0.00185mmHg at 25°C
• Refractive Index: 1.599
• Storage Temp.: 2-8°C
• Water Solubility: Insoluble in water.
• BRN: 2039221
• CAS DataBase Reference: 4-VINYLBIPHENYL(CAS DataBase Reference)
• NIST Chemistry Reference: 4-VINYLBIPHENYL(2350-89-2)
• EPA Substance Registry System: 4-VINYLBIPHENYL(2350-89-2)

Safety Data

• Statements: 36/37/38-53
• Safety Statements: 26-36/37/39-35
• WGK Germany: 3
• Hazardous Substances Data: 2350-89-2(Hazardous Substances Data)

Usage

Uses

4-Vinylbiphenyl intermediate is used in organic synthesis and in chemical research.

InChI:InChI=1/C14H12/c1-2-12-8-10-14(11-9-12)13-6-4-3-5-7-13/h2-11H,1H2

Upstream product

• 3562-73-0 1-(4-phenyl-phenyl)-1-ethanol 
• 980-09-6 2-phthalimido-1-biphenyl-4-yl-1-ethanone 
• 58114-03-7 4-(1-chloroethyl)-1,1′-biphenyl 
• 917-64-6 methyl magnesium iodide 
• 134261-77-1 4-(4-Biphenylyl)-3-thiapentane-1-thiol 
• 134261-69-1 2-biphenyl-4-yl-1,3-dithiolane 
• 104586-12-1 (2-Biphenyl-4-yl-ethyl)-trimethyl-stannane 
• 74-85-1 ethene 
• 92-66-0 4-bromo-1,1'-biphenyl 
• 2039-82-9 1-bromo-4-ethenyl-benzene 
• 98-80-6 phenylboronic acid 
• 87199-17-5 4-formylphenylboronic acid, 
• 1779-49-3 Methyltriphenylphosphonium bromide 
• 13116-27-3 4-iodophenylhydrazine 

Downstream Products

• 20884-11-1 4-Methoxy-4'-phenyl-stilben 
• 20883-14-1 4-Methoxy-3-nitro-4'-phenyl-stilben 
• 263-06-9 6H,12H-Dibenzo<1,5>dithiocin 
• 120229-37-0 3,4-Dihydro-2-(4-biphenylyl)-2H-1-benzothiopyran 
• 120229-46-1 3,4-Dihydro-3-(4-biphenylyl)-2H-1-benzothiopyran 
• 36099-26-0 2-([1,1′-biphenyl]-4-yl)oxirane 
• 92-91-1 biphenyl-4-acetaldehyde 
• 61502-90-7 4-Biphenylacetaldehyde 

Relevant articles and documents

Nickel-catalyzed vinylation of aryl chlorides and bromides with vinyl ZnBr · MgBrCl

The Ni-catalyzed cross-coupling of aryl halides and vinylzinc bromide for the synthesis of styrene derivatives was investigated. Of the catalysts surveyed, the combination of Ni(acac)2 and Xantphos was found to be the most effective for this cr

Functionalized styrene synthesis via palladium-catalyzed C[sbnd]C cleavage of aryl ketones

We report herein the synthesis of functionalized styrenes via palladium-catalyzed Suzuki–Miyaura cross-coupling reaction between aryl ketone derivatives and potassium vinyltrifluoroborate. The employment of pyridine-oxazoline ligand was the key to the cleavage of unstrained C[sbnd]C bond. A variety of functional groups and biologically important moleculars were well tolerated. The orthogonal Suzuki–Miyaura coupling demonstrated the synthetic practicability.

Charge Neutral [Cu2L2] and [Pd2L2] Metallocycles: Self-Assembly, Aggregation, and Catalysis

A range of morphologically distinct metallosupramolecular Cu(II) and Pd(II) complexes has been constructed, based on the tritopic ligand 1,1′,1″-(benzene-1,3,5-triyl)tris(4,4-dimethylpentane-1,3-dione) (H3L). By control of the reaction conditions, it is possible to generate distinct coordination assemblies possessing either macrocyclic or polymeric structures and more importantly distinct activity in catalysis of the Suzuki-Miyaura cross-coupling.

Nickel-Catalyzed Reductive Cross-Coupling of Aryl Bromides with Vinyl Acetate in Dimethyl Isosorbide as a Sustainable Solvent

A nickel-catalyzed reductive cross-coupling has been achieved using (hetero)aryl bromides and vinyl acetate as the coupling partners. This mild, applicable method provides a reliable access to a variety of vinyl arenes, heteroarenes, and benzoheterocycles, which should expand the chemical space of precursors to fine chemicals and polymers. Importantly, a sustainable solvent, dimethyl isosorbide, is used, making this protocol more attractive from the point of view of green chemistry.