23605-13-2

Basic information

• Product Name: (2E,6Z)-2,6-Nonadienoic acid
• Synonyms: (2E,6Z)-2,6-Nonadienoic acid
• CAS NO: 23605-13-2
• Molecular Formula: C9H14O2
• Molecular Weight: 154.21
• Mol File: 23605-13-2.mol
• Article Data: 3

Chemical Properties

• Appearance: /
• CAS DataBase Reference: (2E,6Z)-2,6-Nonadienoic acid(CAS DataBase Reference)
• NIST Chemistry Reference: (2E,6Z)-2,6-Nonadienoic acid(23605-13-2)
• EPA Substance Registry System: (2E,6Z)-2,6-Nonadienoic acid(23605-13-2)

Safety Data

• Hazardous Substances Data: 23605-13-2(Hazardous Substances Data)

Upstream product

• 557-48-2 2E,6Z-nonadienal 
• 141-82-2 malonic acid 
• 6728-31-0 (Z)-4-heptenal 

Relevant articles and documents

INTRAMOLECULAR CYCLOADDITION REACTIONS OF VINYLKETENES. STEREO- AND REGIOSPECIFIC PREPARATION OF VINYLKETENES FROM α,β-UNSATURATED ACID CHLORIDES.

Treatment of α,β-unsaturated acid chlorides 5, 6, 14, 17, and 18 with NEt3 in toluene at reflux generates, stereo- and regiospecifically, the vinylketene which undergoes a facile intramolecular cycloaddition.

Enantioselective CuH-Catalyzed Hydroacylation Employing Unsaturated Carboxylic Acids as Aldehyde Surrogates

The direct asymmetric copper hydride (CuH)-catalyzed coupling of α,β-unsaturated carboxylic acids to aryl alkenes to access chiral α-aryl dialkyl ketones is reported. A variety of substrate substitution patterns, sensitive functional groups, and heterocycles are tolerated in this reaction, which significantly expands the range of accessible products compared with existing hydroacylation methodology. Although mechanistic studies are ongoing, we propose that CuH-catalyzed silylation of unsaturated acids occurs to access a uniquely effective acyl electrophilic coupling partner.