237736-41-3Relevant articles and documents
Asymmetric allylic oxidation of bridged-bicyclic alkenes using a copper-catalysed symmetrising-desymmetrising Kharasch-Sosnovsky reaction
Clark, J. Stephen,Clarke, Melanie-Rose,Clough, John,Blake, Alexander J.,Wilson, Claire
, p. 9447 - 9450 (2007/10/03)
Enantioselective symmetrising-desymmetrising allylic oxidation of racemic bridged bicyclic alkenes using an asymmetric copper-catalysed Kharasch-Sosnovsky reaction has been explored. Good yields and reasonable levels of induction (up to 70% ee) have been
A lipase-mediated route to (+)-juvabione and (+)-epijuvabione from racemic norcamphor
Nagata, Hiroshi,Taniguchi, Takahiko,Kawamura, Mitsuhiro,Ogasawara, Kunio
, p. 4207 - 4210 (2007/10/03)
(+)-Juvabione and (+)-epijuvabione, natural sesquiterpenes exhibiting insect juvenile hormone activity, have been synthesized from (±)-norcamphor via the both enantiomeric intermediates having bicyclo[3.2.1]octane framework by employing a lipase-mediated kinetic ester-hydrolysis reaction and cyclopropane ring-expansion reaction as the key steps.