23784-78-3

Basic information

• Product Name: C₁₄H₁₉NO₂
• Synonyms: C₁₄H₁₉NO₂
• CAS NO: 23784-78-3
• Molecular Weight: 233.31
• Mol File: 23784-78-3.mol
• Article Data: 4

Chemical Properties

• CAS DataBase Reference: C₁₄H₁₉NO₂(CAS DataBase Reference)
• NIST Chemistry Reference: C₁₄H₁₉NO₂(23784-78-3)
• EPA Substance Registry System: C₁₄H₁₉NO₂(23784-78-3)

Safety Data

• Hazardous Substances Data: 23784-78-3(Hazardous Substances Data)

Upstream product

• 107-58-4 N-tert-Butylacrylamide 
• 696-62-8 para-iodoanisole 
• 1052176-56-3 C₁₄H₁₉NO 
• 5720-07-0 4-methoxyphenylboronic acid 

Relevant articles and documents

Synthesis, characterization of palladium hydroxysalen complex and its application in the coupling reaction of arylboronic acids: Mizoroki-Heck type reaction and decarboxylative couplings

(Salen-OH)Pd (1, salen-OHN,N′-bis(3,5-di-hydroxysalicylidene)- ethylenediamine) was prepared by a simple one step reaction and fully characterized by 1H and 13C NMR, IR spectroscopy, and X-ray crystallography. This palladium complex showed good activities as a catalyst in the Mizoroki-Heck-type reaction and the decarboxylative coupling reaction. In the Mizoroki-Heck type reaction, arylboronic acids and alkenes were reacted at 90°C for 3 h in the presence of 2.0 mol% of the palladium complex 1 and AgOAc to give the desired coupled product in good yields. In the decarboxylative coupling reactions, the desired coupled products were obtained in good yields when 0.5 mol% of the palladium complex was employed at room temperature.

Oxidation of aliphatic α,β-unsaturated aldimines to amides specifically by oxone with AlCl3

α,β-Unsaturated aldimines were specifically oxidized to amides with Oxone in the presence of AlCl3 as a Lewis acid in CH2Cl2. No migration of aryl group occurred in the rearrangement reaction. Copyright Taylor & Francis Group, LLC.