23916-48-5Relevant articles and documents
THERMAL TRANSFORMATIONS OF 1,2-CHLOROHYDRINS
Zil'berman, I. E.,Kolesnikov, V. A.,Danov, S. M.,Efremov, R. V.
, p. 542 - 547 (2007/10/02)
The composition of the products and the kinetic parameters were determined for the liquid-phase thermolysis of 2-chloro-1-propanol at 130-160 deg C and of 1,3-dichloro-2-propanol and 2,3-dichloro-1-propanol at 180-200 deg C.The intramolecular dehydrochlorination of the 1,2-chlorohydrins is based on a process of the E1 type with the formation of an enol, which rearranges to the carbonyl compound according to the El'tekov rule; the isomerization of 1,2-chlorohydrins catalyzed by hydrogen chloride and their reaction with hydrogen chloride take place through the formation of a chloronium cation, which is attacked in the first case by a water molecule and in the second by the chloride ion.