24018-00-6Relevant articles and documents
Sodium Hypochlorite Pentahydrate as a Reagent for the Cleavage of trans-Cyclic Glycols
Kirihara, Masayuki,Osugi, Rie,Saito, Katsuya,Adachi, Kouta,Yamazaki, Kento,Matsushima, Ryoji,Kimura, Yoshikazu
, p. 8330 - 8336 (2019/06/24)
Sodium hypochlorite pentahydrate (NaOCl·5H2O) can be used toward the efficient glycol cleavage of trans-cyclic glycols, which are generally resistant to this transformation. Interestingly, the reaction of cis-cyclic glycols with NaOCl·5H2O is slower than that observed for the corresponding trans-isomer. This trans selectivity is in sharp contrast to traditional oxidants used for glycol cleavage. Acyclic glycols can also react efficiently with NaOCl·5H2O to form their corresponding carbonyl compounds in high yield.
Nickel phosphate catalysts
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, (2008/06/13)
Methods for coupling aryl halides or aryl sulfonates to produce biaryls or polyaryls using novel nickel phosphite catalysts are provided.
Syntheses and Chemistry of Some Dibenzazepines
Weitzberg, Moshe,Abu-Shakra, Elias,Azeb, Abdullatif,Aizenshtat, Zeev,Blum, Jochanan
, p. 529 - 536 (2007/10/02)
5-Methyl-, 5,7-dimethyl-, and 5,7-diphenyl-substituted and unsubstituted 5H-dibenzazepines were prepared by two general routes from -2,2'-dicarboxaldehyde.The unsubstituted dibenzazepine was converted into 1a,9b-dihydrophenanthro9,10-