24115-89-7

Basic information

• Product Name: Benzoic acid, 2-nitro-3-(phenylmethoxy)-
• CAS NO: 24115-89-7
• Molecular Formula: C14H11NO5
• Molecular Weight: 273.245
• Mol File: 24115-89-7.mol
• Article Data: 7

Chemical Properties

• CAS DataBase Reference: Benzoic acid, 2-nitro-3-(phenylmethoxy)-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzoic acid, 2-nitro-3-(phenylmethoxy)-(24115-89-7)
• EPA Substance Registry System: Benzoic acid, 2-nitro-3-(phenylmethoxy)-(24115-89-7)

Safety Data

• Hazardous Substances Data: 24115-89-7(Hazardous Substances Data)

Upstream product

• 108-39-4 3-methyl-phenol 
• 5345-42-6 1-methoxy-3-methyl-2-nitro-benzene 
• 4920-80-3 3-methoxy-2-nitrobenzoic acid 
• 4920-77-8 3-methyl-2-nitrophenol 
• 89942-77-8 methyl 3-hydroxy-2-nitrobenzoate 
• 94863-06-6 benzyl 3-benzyloxy-2-nitrobenzoate 
• 602-00-6 3-hydroxy-2-nitrobenzoic acid 
• 533897-93-7 3-benzyloxy-2-nitrobenzoic acid methyl ester 

Downstream Products

• 70441-00-8 N-(2-amino-3-hydroxy-benzoyl)-glycine 
• 872311-04-1 N-(3-benzyloxy-2-nitro-benzoyl)-glycine 
• 177477-63-3 tert-butyl 3-(benzyloxy)-2-nitrophenylcarbamate 
• 432029-31-7 4'-chloro-2'-[(5-chloro-2-pyridyl)carbamoyl]-6'-hydroxyl-1-isopropylpiperidine-4-carboxanilide hydrochloride 
• 432029-33-9 4'-bromo-2'-[(5-chloro-2-pyridyl)carbamoyl]-6'-hydroxyl-1-isopropylpiperidine-4-carboxanilide hydrochloride 
• 432029-32-8 4'-chloro-2'-[(5-chloro-2-pyridyl)carbamoyl]-6'-hydroxyl-1-isopropylpiperidine-4-carboxanilide 
• 365462-84-6 2-amino-5-bromo-N-(5-chloro-2-pyridyl)-3-hydroxybenzamide 
• 365462-83-5 2-amino-5-chloro-N-(5-chloro-2-pyridyl)-3-hydroxybenzamide 
• 365462-81-3 2-amino-N-(5-chloro-2-pyridyl)-3-hydroxybenzamide 
• 1086561-89-8 2-(3-benzyloxy-2-nitro-benzoylamino)-3-hydroxy-benzoic acid methyl ester 
• 33145-22-1 5-nitro-3-benzyloxy benzoyl chloride 
• 61535-25-9 3-Benzyloxy-2-iodo-benzoic acid 
• 61559-83-9 3-Benzyloxy-2-iodo-benzoyl chloride 
• 80279-25-0 11-epi-tilivalline 

Relevant articles and documents

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Asymmetric allylation and vinylation of aldehydes with allyl halides and vinyl halides have been achieved using the chromium(II)-oxazoline catalyst. The catalyst promotes the highly efficient enantioselective Nozaki–Hiyama-Kishi (NHK) allylation of aldehydes using allyl bromide, producing the corresponding homoallylic alcohols in good yields (up to 84%) and a high level of enantioselectivity (up to 98% ee). Meanwhile, the NHK vinylation of aldehydes produce desired allylic alcohols in satisfactory yields (up to 88%) and a high level of enantioselectivity (up to 97% ee). We developed a reliable and milder protocol for preparing chiral homoallylic and allylic alcohols.

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