2418-31-7Relevant articles and documents
Synthesis of α,β-Disubstituted Acrylates via Galat Reaction
Xavier, Tania,Condon, Sylvie,Pichon, Christophe,Le Gall, Erwan,Presset, Marc
supporting information, p. 6135 - 6139 (2019/08/28)
Galat reactions between aldehydes and substituted malonic acids half oxyester were found to be efficiently catalyzed by morpholine in refluxing toluene. This transformation allows the stereoselective synthesis of diverse α,β-disubstituted acrylates in moderate to good yields. This method constitutes an attractive alternative to existing methods in terms of scope and eco-compatibility.
NEW YLIDE ANIONS. A VINYL ANION EQUIVALENT FOR SUBSTITUTED FUMARATE ESTERS
Cooke, Manning P.
, p. 381 - 384 (2007/10/02)
A new type of ylide anion is reported which upon alkylation and elimination of triphenylphosphine serves as a vinyl anion equivalent.
