2460-77-7 Usage
Description
2,5-Di-tert-butyl-1,4-benzoquinone (DTBBQ) is a 2,5-disubstituted quinone that has been identified as an antibacterial compound. It is derived from marine Streptomyces sp. VITVSK1 and has been studied for its pressure dependence on the intramolecular and intermolecular migration rates of Na+ and K+ using a high-pressure EPR technique. DTBBQ is characterized by its yellow to golden crystalline powder appearance.
Uses
Used in Pharmaceutical Industry:
2,5-Di-tert-butyl-1,4-benzoquinone is used as an antibacterial agent for its ability to inhibit bacterial growth. It is particularly valuable in the development of new antibiotics to combat drug-resistant bacteria due to its natural origin and unique chemical structure.
Used in Chemical Research:
DTBBQ serves as a subject of study in chemical research, specifically in understanding the pressure dependence of ion migration rates. This knowledge can be applied to various fields, including material science and the development of new technologies that rely on ion movement.
Used in Marine Biology:
As a compound isolated from marine Streptomyces sp. VITVSK1, 2,5-Di-tert-butyl-1,4-benzoquinone contributes to the study of marine microorganisms and their potential applications in medicine and biotechnology. It can be used to explore the biodiversity of marine ecosystems and the bioactive compounds they produce.
Synthesis Reference(s)
The Journal of Organic Chemistry, 46, p. 4545, 1981 DOI: 10.1021/jo00335a045Synthetic Communications, 10, p. 615, 1980 DOI: 10.1080/00397918008063598Tetrahedron Letters, 35, p. 5083, 1994 DOI: 10.1016/S0040-4039(00)73327-2
Flammability and Explosibility
Flammable
Check Digit Verification of cas no
The CAS Registry Mumber 2460-77-7 includes 7 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 4 digits, 2,4,6 and 0 respectively; the second part has 2 digits, 7 and 7 respectively.
Calculate Digit Verification of CAS Registry Number 2460-77:
(6*2)+(5*4)+(4*6)+(3*0)+(2*7)+(1*7)=77
77 % 10 = 7
So 2460-77-7 is a valid CAS Registry Number.
InChI:InChI=1/C14H20O2/c1-13(2,3)9-7-12(16)10(8-11(9)15)14(4,5)6/h7-8H,1-6H3
2460-77-7Relevant articles and documents
Practical Large-Scale Oxidation of 1,4-Hydroquinones to 1,4-Benzoquinones Using Hydrogen Peroxide/Catalytic Diphenyl Diselenide
Pratt, Daniel V.,Ruan, Fuqiang,Hopkins, Paul B.
, p. 5053 - 5055 (1987)
-
-
Cohen
, p. 1057,1063 (1947)
-
Saito et al.
, p. 239 (1970)
The impact of an isoreticular expansion strategy on the performance of iodine catalysts supported in multivariate zirconium and aluminum metal-organic frameworks
Tahmouresilerd, Babak,Moody, Michael,Agogo, Louis,Cozzolino, Anthony F.
supporting information, p. 6445 - 6454 (2019/05/24)
Iodine functionalized variants of DUT-5 (Al) and UiO-67 (Zr) were prepared as expanded-pore analogues of MIL-53 (Al) and UiO-67 (Zr). They were prepared using a combination of multivariate and isorecticular expansion strategies. Multivariate MOFs with a 25% iodine-containing linker was chosen to achieve an ideal balance between a high density of catalytic sites and sufficient space for efficient diffusion. Changes to the oxidation potential of the catalyst as a result of the pore-expansion strategy led to a decrease in activity with electron rich substrates. On the other hand, these larger frameworks proved to be more efficient catalysts for substrates with higher oxidation potentials. Recyclability tests for these larger MOFs showed sustained catalytic activity over multiple recycles.
Preparation and catalytic performance of perfluorosulfonic acid-functionalized carbon nanotubes
Zhang, Mengxiao,Li, Cuican,Hua, Weiming,Yue, Yinghong,Gao, Zi
, p. 1874 - 1882 (2015/09/28)
Perfluorosulfonic acid-functionalized carbon nanotubes were prepared by liquid deposition of the perfluorosulfonic acid-polytetrafluoroethylene copolymer and characterized by N2 adsorption, scanning electron microscopy, transmission electron mi
