24625-65-8

Basic information

• Product Name: Diphenylphosphinodithioic acid 4,6-dimethylpyrimidin-2-yl ester
• Synonyms: Diphenylphosphinodithioic acid 4,6-dimethylpyrimidin-2-yl ester
• CAS NO: 24625-65-8
• Molecular Formula: C₁₈H₁₇N₂PS₂
• Molecular Weight: 356.44
• Mol File: 24625-65-8.mol
• Article Data: 1

Chemical Properties

• Appearance: /
• CAS DataBase Reference: Diphenylphosphinodithioic acid 4,6-dimethylpyrimidin-2-yl ester(CAS DataBase Reference)
• NIST Chemistry Reference: Diphenylphosphinodithioic acid 4,6-dimethylpyrimidin-2-yl ester(24625-65-8)
• EPA Substance Registry System: Diphenylphosphinodithioic acid 4,6-dimethylpyrimidin-2-yl ester(24625-65-8)

Safety Data

• Hazardous Substances Data: 24625-65-8(Hazardous Substances Data)

Upstream product

• 4472-44-0 2-chloro-4,6-dimethylpyrimidine 
• 5827-17-8 sodium diphenylphosphinodithioate 

Downstream Products

• 1707-03-5 diphenyl-phosphinic acid 
• 22126-11-0 2,2'-bis(4,6-dimethylpyrimidin-2-yl) sulfide 

Relevant articles and documents

Reaction of pyrimidyl esters of some phosphorus acids with isomeric butyl alcohols

A series of pyrimidyl esters of some phosphorus acids was prepared with the purpose of investigation of their reaction with isomeric butyl alcohols. According to31P NMR data, the obtained phosphates all are capable of phosphorylating isomeric butyl alcohols. The reactions with diphenyl (4-oxo-3,4-dihydro-2-pyrimidyl) phosphate and diphenyl (2-pyrimidyl) phosphate occur in quantitative yield under mild conditions, and the reactions with diphenyl (4,6-dimethyl-2-pyrimidyl) phosphate and dibutyl (4,6-dimethyl-2-pyrimidyl) phosphate require severe conditions to occur. In the latter two cases, certain reaction selectivity was observed, depending on the nature of the solvent and some other factors. Pyrimidyl esters of sulfur-containing phosphorus acids do not react with isomeric butyl alcohols under the studied conditions.