2466-25-3

Basic information

• Product Name: 13-Hydroxy-13,17-seco-5α-androstan-17-oic acid δ-lactone
• Synonyms: 13-Hydroxy-13,17-seco-5α-androstan-17-oic acid δ-lactone;D-Homo-17a-oxa-5α-androstan-17-one
• CAS NO: 2466-25-3
• Molecular Formula: C19H30O2
• Molecular Weight: 290.4403
• Mol File: 2466-25-3.mol
• Article Data: 5

Chemical Properties

• Appearance: /
• CAS DataBase Reference: 13-Hydroxy-13,17-seco-5α-androstan-17-oic acid δ-lactone(CAS DataBase Reference)
• NIST Chemistry Reference: 13-Hydroxy-13,17-seco-5α-androstan-17-oic acid δ-lactone(2466-25-3)
• EPA Substance Registry System: 13-Hydroxy-13,17-seco-5α-androstan-17-oic acid δ-lactone(2466-25-3)

Safety Data

• Hazardous Substances Data: 2466-25-3(Hazardous Substances Data)

Upstream product

• 963-74-6 5alpha-androstan-17-one 
• 96616-63-6 17a-oxa-D-homo-5α-androstan-17α-ol 
• 1912-61-4 5β-androstan-17-one 

Relevant articles and documents

Concerning the mechanism of the characteristic ring D fragmentation of steroids

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Ceric ammonium nitrate (CAN) catalyzed Baeyer-Villiger oxidation of carbonyl compounds, specially 20-oxosteroids

The role of ceric ammonium nitrate (CAN) as an effective catalyst in the peracid induced Baeyer-Villiger oxidation of carbonyl compounds with special reference to steroids has been demonstrated.

REPLACEMENT OF A CARBONYL GROUP OF CYCLIC KETONES BY AN OXYGEN ATOM: A FOUR-STEP TRANSFORMATION OF CYCLIC KETONES INTO CYCLIC ETHERS

We describe a new and versatile method for transforming cyclic ketones into cyclic ethers with the same ring size in which the chirality adjacent to the carbonyl group of the ketones is retained.