24764-92-9

Basic information

• Product Name: Benzenamine, N,N'-1,2-ethanediylidenebis[4-methyl-
• CAS NO: 24764-92-9
• Molecular Formula: C16H16N2
• Molecular Weight: 236.316
• Mol File: 24764-92-9.mol
• Article Data: 10

Chemical Properties

• CAS DataBase Reference: Benzenamine, N,N'-1,2-ethanediylidenebis[4-methyl-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzenamine, N,N'-1,2-ethanediylidenebis[4-methyl-(24764-92-9)
• EPA Substance Registry System: Benzenamine, N,N'-1,2-ethanediylidenebis[4-methyl-(24764-92-9)

Safety Data

• Hazardous Substances Data: 24764-92-9(Hazardous Substances Data)

Upstream product

• 99-99-0 1-methyl-4-nitrobenzene 
• 174647-91-7 4-formyl-3,3-dimethyl-1-(p-tolyl)-azetidin-2-one 
• 106-49-0 p-toluidine 
• 174647-97-3 [(Z)-p-Tolylimino]-acetaldehyde 
• 131543-46-9 Glyoxal 

Downstream Products

• 51100-99-3 1,4-bis-(3-methyl-isoxazol-5-yl)-N,N'-di-p-tolyl-butane-2,3-diamine 
• 41996-52-5 4-methylphenylamino-(1,3-dioxo-2,3-dihydro-1H-inden-2-ylidene)ethanenitrile 
• 74552-73-1 Ru₂(CO)4(p-tolyl-N=CHCH=N-p-tolyl)2 
• 200574-31-8 Pt(CH₃)4((CH₃C₆H₄NCH)2) 
• 200574-33-0 [(N,N'-di-p-tolyl-1,4-diazabutadiene)bis(2,4,6-trimethylphenyl)platinum(II)] 
• 201802-47-3 Pt(CH₃)2((CH₃C₆H₄NCH)2)^(1-) 
• 201802-50-8 Pt(CH₃)4((CH₃C₆H₄NCH)2)^(1-) 
• 201802-59-7 Pt((CH₃)3C₆H₂)2((CH₃C₆H₄NCH)2)^(1-) 
• 174647-91-7 4-formyl-3,3-dimethyl-1-(p-tolyl)-azetidin-2-one 
• 84289-22-5 2,3-diphenyl-1-p-tolyl-pyrrole 
• 84289-15-6 4,5-Diphenyl-1-p-tolyl-2-[(E)-p-tolylimino-methyl]-1,2-dihydro-pyrrol-3-one 
• 115998-60-2 2,3-bis(4-methylphenylimino)propanenitrile 

Relevant articles and documents

Heteroleptic 1,4-Diazabutadiene Complexes of Ruthenium: Synthesis, Characterization and Utilization in Catalytic Transfer Hydrogenation

Reaction of [Ru(trpy)Cl3] with 1,4-diazabutadienes (p-RC6H4N=C(H)-(H)C=NC6H4R-p; R = OCH3, CH3, H and Cl; abbreviated as L-R) in refluxing ethanol in the presence of triethylamine has afforded a family of complexes, isolated as perchlorate salts, of type [Ru(trpy)(L-R)Cl]ClO4 [depicted as complexes 1 (R = OCH3), 2 (R = CH3), 3 (R = H) and 4 (R = Cl)]. Crystal structures of complexes 1, 2 and 4 have been determined, and structure of complex 3 has been optimized by DFT method. The 1,4-diazabutadiene ligand in each complex is bound to ruthenium as a N,N-donor forming five-membered chelate. Complexes 1–4 catalyze transfer hydrogenation of aryl aldehydes to the corresponding alcohols with high (ca. 106) TON. They are also found to catalyze transfer hydrogenation of aryl ketones to corresponding secondary alcohols, but with much less efficiency. Catalytic transfer hydrogenation of nitroarenes to the corresponding amines has also been achieved.

BIS-IMINE TITANIUM COMPLEX, CATALYTIC SYSTEM COMPRISING SAID BIS-IMINE TITANIUM COMPLEX AND PROCESS FOR THE (CO)POLYMERIZATION OF CONJUGATED DIENES

Bis-imine titanium complex having general formula (I): wherein: R1 and R2, mutually identical or different, represent a hydrogen atom; or are selected from linear or branched, optionally halogenated, C1-C20 alky

Steric demands in the formation of heteroleptic Cu(I) complexes with α-diimines and triphenylphosphine

The synthesis and the study of the molecular structure of a series of heteroleptic copper(I) compounds with triphenylphosphine and α-diimines presenting a varying degree of bulk at their chelating cite is reported. The most sterically crowded diimine acts as a monodentate ligand towards copper(I) promoting bridging of the halogen atom present in the metal coordination sphere and formation of a dimer. Evidence for this behavior is obtained from the electronic spectra and semiempirical quantum chemical calculations with MOPAC. Steric demands in all the studied compounds preclude coordination of silver(I) under similar reaction conditions.