24948-81-0Relevant articles and documents
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Deno,N.C. et al.
, p. 438 - 440 (1971)
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An insight of the reactions of amines with trichloroisocyanuric acid
De Luca, Lidia,Giacomelli, Giampaolo
, p. 2180 - 2184 (2007/10/03)
The reaction between amines or α-aminoacids with trichloroisocyanuric acid is studied under various conditions: N,N-dichloroamines, nitriles and ketones can be obtained from primary amines, while free aminoacids undergo oxidative decarboxylation to the corresponding nitrile of one less carbon atom.
REACTION OF TERVALENT PHOSPHORUS COMPOUNDS WITH STERICALLY HINDERED N-CHLOROAMINES
Kolodiazhnyi, Oleg I.,Golovatyi, Oleg R.
, p. 133 - 142 (2007/10/02)
Reaction of tervalent phosphorus compounds with sterically hindered N-halogenoamines (1,2) proceeds via the formation of halogenophosphonium intermediates (3), containing an anion R2N-.Intermediates react with alcohols to afford alkoxyphosphonium salts (6), transform into halogenophosphonium salts (4) or P-halogenoylids.Sterical hindrances at the nitrogen atom of intermediates (3) favour the formation of P-halogenoylids.The P-chloroylid (10) exists in the chlorotropic equilibrium with the α-chloroalkylphosphine (16). Key words: Sterical hindered N-halogenoamines, N-chlorodiisopropylamine, N-chloro-trimethylsilyl-tert-butylamine, alkoxyphosphonium salts, P-chloroylids, 1,2-CP-chlorotropy, positive halogen, NMR spectra, halogenophilic substitution.