24953-82-0

Basic information

• Product Name: 1,3-dimethoxy-4,6-dimethylbenzene
• Synonyms: 1,3-dimethoxy-4,6-dimethylbenzene
• CAS NO: 24953-82-0
• Molecular Weight: 166.22
• Mol File: 24953-82-0.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: 1,3-dimethoxy-4,6-dimethylbenzene(CAS DataBase Reference)
• NIST Chemistry Reference: 1,3-dimethoxy-4,6-dimethylbenzene(24953-82-0)
• EPA Substance Registry System: 1,3-dimethoxy-4,6-dimethylbenzene(24953-82-0)

Safety Data

• Hazardous Substances Data: 24953-82-0(Hazardous Substances Data)

Upstream product

• 24988-36-1 4,6-dibromo-1,3-dimethoxybenzene 
• 74-88-4 methyl iodide 
• 38064-90-3 2,4-dimethoxytoluene 
• 67-56-1 methanol 
• 105-67-9 2,4-Xylenol 
• 70264-63-0 4-chloro-2,4-dimethylcyclohexa-2,5-dienone 
• 615-89-4 2,4-dimethyl-5-hydroxyphenol 
• 7149-91-9 2,4-dimethoxy-5-methyl-benzaldehyde 
• 70853-94-0 N-(2,4-dimethylphenyl)hydroxylamine 
• 613-45-6 2,4-Dimethoxybenzaldehyde 
• 1198-37-4 2,4-dimethylquinoline 

Downstream Products

• 37467-68-8 1-(2,6-dihydroxy-3,5-dimethyl-phenyl)-ethanone 
• 91971-25-4 2,6-dimethoxy-3,5-dimethylbenzoic acid 
• 24953-83-1 1,5-Dimethoxy-2,4-dimethyl-cyclohexadien-1,4 
• 615-89-4 2,4-dimethyl-5-hydroxyphenol 

Relevant articles and documents

Compound

PROBLEM TO BE SOLVED: To provide a compound capable of forming a color filter excellent in heat resistance. SOLUTION: The present invention provides a compound represented by formula (I). [In formula (I), R1-R8 independently represen

Electrophilic Chlorination of 4-Methylphenols with Molecular Chlorine. Synthesis of Dimethoxy Aromatics by Methanolysis of 4-Chloro-4-methylcyclcohexa-2,5-dienones

The chlorination of p-cresol (1a), 2,4-dimethylphenol (1b), 3,4-dimethylphenol (1c), 2,4,5-trimethylphenol (1d), 2,4,6-trimethylphenol (1e) and the various possible mono- and dichloro derivatives of these phenols (3a-d, 6a and 6 c) with molecular chlorine was investigated in dichloromethane or dimethyl formamide solution.The 2,6-substituted p-cresol derivatives all give quantitative yields of 4-chloro-4-methylcyclohexa-2,5-dienones (5b, 5d, 7a, 7c and 2e), whereas the less substituted p-cresol derivatives give a 20-25percent yield of corresponding 4-chloro-4-methylcyclohexa-2,5-dienones (2a-d, 5a and 5c), the other products being chlorinated phenols.Treatment of 4-chloro-4-methylcyclohexa-2,5-dienones with at least one of the double bonds of the ring unsubstituted (2a-c and 4a) with methanol gave a quantitative yield of a 1,3-dimethoxybenzene derivative (9a-c and 10), whereas similar treatment of 4-chloro-2,4,5-trimethylcyclohexa-2,5-dienone (2d) gave 5-methoxy-2,3-dimethylbenzyl methyl ether (11).Treatment of the other 4-chlorodienones with methanol gave the corresponding 4-methoxydienones.Electrophilic chlorination of certain p-cresol derivatives followed by methanolysis hence is a facile although low-yield method for 3-methoxylation or selective side chain oxidation of these p-cresol derivatives.