25080-84-6Relevant articles and documents
Metal-Free Enantioselective Oxidative Arylation of Alkenes: Hypervalent-Iodine-Promoted Oxidative C?C Bond Formation
Shimogaki, Mio,Fujita, Morifumi,Sugimura, Takashi
supporting information, p. 15797 - 15801 (2016/12/16)
The enantioselective oxyarylation of (E)-6-aryl-1-silyloxylhex-3-ene was achieved using a lactate-based chiral hypervalent iodine(III) reagent in the presence of boron trifluoride diethyl etherate. The silyl ether promotes the oxidative cyclization, and enhances the enantioselectivity. In addition, the corresponding aminoarylation was achieved.
OPHTHALMIC COMPOSITIONS FOR TREATING OCULAR HYPERTENSION
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Page/Page column 30, (2008/06/13)
This invention relates to the use of potent potassium channel blockers or a formulation thereof in the treatment of glaucoma and other conditions which leads to elevated intraoccular pressure in the eye of a patient. This invention also relates to the use of such compounds to provide a neuroprotective effect to the eye of mammalian species, particularly humans.
Rate and Regioselectivity of Hydrogenolysis of Some Phenyl-Substituted Cyclopropanes
Brueckner, Christiane,Reissig, Hans-Ulrich
, p. 627 - 630 (2007/10/02)
Several phenyl-substituted cyclopropane derivatives were investigated regarding rate and regiochemistry of their hydrogenolysis.The following reactivity sequence has been established: 1 2 4 7 9.Substituent effects are discussed and compared to those reported for monoactivated cyclopropanes.