25187-18-2

Basic information

• Product Name: 6-METHYL-2-PHENYLQUINOXALINE
• Synonyms: 6-METHYL-2-PHENYLQUINOXALINE
• CAS NO: 25187-18-2
• Molecular Formula: C₁₅H₁₂N₂
• Molecular Weight: 220.27
• Mol File: 25187-18-2.mol
• Article Data: 36

Chemical Properties

• Boiling Point: 378.6°Cat760mmHg
• Flash Point: 164°C
• Appearance: /
• Density: 1.149g/cm³
• Vapor Pressure: 1.35E-05mmHg at 25°C
• Refractive Index: 1.647
• CAS DataBase Reference: 6-METHYL-2-PHENYLQUINOXALINE(CAS DataBase Reference)
• NIST Chemistry Reference: 6-METHYL-2-PHENYLQUINOXALINE(25187-18-2)
• EPA Substance Registry System: 6-METHYL-2-PHENYLQUINOXALINE(25187-18-2)

Safety Data

• Hazardous Substances Data: 25187-18-2(Hazardous Substances Data)

Usage

InChI:InChI=1/C15H12N2/c1-11-7-8-13-14(9-11)16-10-15(17-13)12-5-3-2-4-6-12/h2-10H,1H3

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Downstream Products

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Relevant articles and documents

A heterogeneous catalytic strategy for facile production of benzimidazoles and quinoxalines from primary amines using the Al-MCM-41 catalyst

This study reports a straightforward heterogeneous catalytic (Al-MCM-41) approach to synthesize nitrogen heterocycle moieties from primary amines under solvent-free conditions. The Al-MCM-41 catalyst was prepared using a hydrothermal method and characterized by various analytical techniques. The probability and limitations of the catalytic methodology were presented with various substrates. The catalytic method grants an attractive route to a wide variety of benzimidazole and quinoxaline moieties with good to excellent yields. The gram scale reaction and reusability (up to five cycles) of the Al-MCM-41 catalyst would greatly benefit industrial applications. This journal is

Iridium-Catalyzed Carbenoid Insertion of Sulfoxonium Ylides for Synthesis of Quinoxalines and β-Keto Thioethers in Water

Sulfoxonium ylides as safe carbene precursors are described for iridium-catalyzed carbene insertions and annulation, providing a facile and green approach to access a variety of quinoxaline derivatives in water. This water-mediated method also allows the preparation of β-keto thioethers under mild condition.

Application of a reusable Co-based nanocatalyst in alcohol dehydrogenative coupling strategy: Synthesis of quinoxaline and imine scaffolds

A nitrogen doped carbon supported cobalt catalyzed efficient synthesis of imines and quinoxaline motifs is reported. Co(OAc)2-Phen/Carbon-800 (Co-phen/C-800) showed the superior reactivity compared to other materials prepared at different temperature, in the synthesis of quinoxalines by the coupling between diamines and diols. Moreover, applying the transfer hydrogenation and acceptorless dehydrogenative coupling strategy, imines and quinoxaline derivatives were synthesized from the nitro compounds. The practical applicability of this protocol was demonstrated by the gram-scale synthesis and the reusability of the catalyst upto 8th cycle. Furthermore, several kinetic experiments were carried out to realize the probable mechanism.