25343-67-3Relevant articles and documents
Reaction of Thiocarbonyl Fluoride Generated from Difluorocarbene with Amines
Yu, Jiao,Lin, Jin-Hong,Xiao, Ji-Chang
supporting information, p. 16669 - 16673 (2017/12/07)
The reaction of thiocarbonyl fluoride, generated from difluorocarbene, with various amines under mild conditions is described. Secondary amines, primary amines, and o-phenylenediamines are converted to thiocarbamoyl fluorides, isothiocyanates, and difluoromethylthiolated heterocycles, respectively. Thiocarbamoyl fluorides were further transformed into trifluoromethylated amines by using a one-pot process. Thiocarbonyl fluoride is generated in situ and is rapidly fully converted in one pot under mild conditions; therefore, no special safety precautions are needed.
Phosphine-free conversion of alcohols into alkyl thiocyanates using trichloroisocyanuric acid/NH4SCN
Azadi, Roya,Mokhtari, Babak,Makaremi, Mohamad-Ali
experimental part, p. 77 - 80 (2012/03/26)
A convenient and efficient phosphine-free procedure for the one-pot conversion of primary, secondary and tertiary alcohols into the corresponding alkyl thiocyanates or alkyl isothiocyanates is described using trichloroisocyanuric acid/NH4SCN.
Oxalic acid-catalyzed reaction of alcohols with NaSCN: The effects of additives NaI and i2
Miyake, Hideyoshi,Nakao, Yuichi,Sasaki, Mitsuru
, p. 1262 - 1263 (2008/02/05)
Oxalic acid-mediated conversion of alcohols to thiocyante and/or isothiocyanate is described. Aliphatic tertiary alcohols give isothiocyanate by the reaction with NaSCN in the presence of I2, whereas they give thiocyanate without it. Copyright