25662-41-3Relevant articles and documents
Diastereocontrol in the synthesis of models of rings C and D of phorbol: Directing effect of an ether substituent on lithium carbenoid mediated cyclopropanation
Drew, Michael G. B.,Harwood, Laurence M.,Macias-Sanchez, Antonio J.,Scott, Richard,Thomas,Uguen, Daniel
, p. 2311 - 2313 (2001)
The diastereocomplementarity of halo- and alkylcarbenes (paths a and b, respectively) was shown in the cyclopropanation reaction of 1. The conversion of 1 into 7,7-dimethylbicyclo[4.1.0]heptan-1,2-diols (±)-2 and (±)-3 represents an important transformati