25713-23-9Relevant articles and documents
Synthesis of α-amino and α-hydroxy acids under volcanic conditions: implications for the origin of life
Huber, Claudia,Eisenreich, Wolfgang,W?chtersh?user, Günter
scheme or table, p. 1069 - 1071 (2010/04/05)
Facile synthesis of α-hydroxy and α-amino acids is observed at temperatures from 145 to 280 °C with catalytic Ni2+, with cyano ligands as source for C and N, and with CO as a reductant and as a source for C. Implications for the problem of the origin of life are discussed.
Stereoselective synthesis of stable isotope-labeled L-α-amino acids: Electrophilic amination of oppolzer's acyl sultams in the synthesis of L-[15N]alanine, L-[15N]valine, L-[15N]leucine, L-[15N]phenylalanine and
Lodwig,Unkefer
, p. 239 - 248 (2007/10/03)
Using 1-chloro-1-[15N]nitrosocyclohexane, we have prepared five L-[α-15N]amino acids. The stereoselective electophillic hydroxyamination of (S)-acylbornane-10,2-sultams, followed by Zn(o)/H+ reduction, and alkaline cleavag