2593-28-4

Basic information

• Product Name: Benzamide, 3-bromo-N-hydroxy-
• CAS NO: 2593-28-4
• Molecular Formula: C7H6BrNO2
• Molecular Weight: 216.034
• Mol File: 2593-28-4.mol
• Article Data: 10

Chemical Properties

• CAS DataBase Reference: Benzamide, 3-bromo-N-hydroxy-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzamide, 3-bromo-N-hydroxy-(2593-28-4)
• EPA Substance Registry System: Benzamide, 3-bromo-N-hydroxy-(2593-28-4)

Safety Data

• Hazardous Substances Data: 2593-28-4(Hazardous Substances Data)

Upstream product

• 24398-88-7 ethyl 3-bromobenzoate 
• 1711-09-7 3-bromobenzoyl chloride 
• 15852-73-0 (3-Bromophenyl)methanol 
• 585-76-2 m-bromobenzoic acid 
• 618-89-3 methyl 3-bromobenzoate 

Downstream Products

• 1427180-45-7 (3-bromophenyl)formamido 2,2-dimethylpropanoate 
• 53463-67-5 2-(3-Bromo-phenyl)-4H-3,1-benzoxazin-4-one 
• 37831-25-7 N-(3-bromophenyl)formamide 

Relevant articles and documents

Three-Component 1,2-Carboamidation of Bridged Bicyclic Alkenes via RhIII-Catalyzed Addition of C-H Bonds and Amidating Reagents

A three-component method is described for the preparation of syn-1,2-disubstituted bridged bicyclic compounds. The reaction was demonstrated for readily available aromatic and heteroaromatic C-H bond substrates with tertiary and secondary amide, lactam, p

Palladium-Catalyzed 5-exo-dig Cyclization Cascade, Sequential Amination/Etherification for Stereoselective Construction of 3-Methyleneindolinones

An cascade intramolecular 5-exo-dig cyclization of N-(2-iodophenyl)propiolamides and sequential amination/etherification (with N-hydroxybenzamides, phenyl hydroxycarbamate) protocol for the synthesis of amino- and phenoxy-substituted 3-methyleneindolinones using unexpensive Pd(PPh3)4 as catalyst has been developed. The protocol enables the assembly of structurally important oxindole cores featuring moderate functional group tolerance (particularly the halo group), affording a broad spectrum of products with diverse substituents in good to excellent yields. (Figure presented.).

Rhodium(III)-catalyzed C4-amidation of indole-oximes with dioxazolones: Via C-H activation

A novel method for the Rh(III)-catalyzed oxime-directed C-H amidation of indoles with dioxazolones has been developed. This strategy provides an exclusive site selectivity and the directing group can be easily removed. This transformation features a wide substrate scope, good functional group tolerance and excellent yields, and may serve as a significant tool to construct structurally diverse indole derivatives for the screening of potential pharmaceuticals in the future. This journal is